102918-08-1Relevant academic research and scientific papers
Activation of the S-H group in Fe(μ2-SH)Fe clusters: S-H bond strengths and free radical reactivity of the Fe(μ2-SH)Fe cluster
Franz, James A.,Lee, Suh-Jane,Bowden, Thomas A.,Alnajjar, Mikhail S.,Appel, Aaron M.,Birnbaum, Jerome C.,Bitterwolf, Thomas E.,Dupuis, Michel
, p. 15212 - 15224 (2009)
Absolute rate constants were determined for the abstraction of hydrogen atoms from (OC)3Fe(μ-SH)2Fe(CO)3 (Fe 2S2H2) and (OC)3Fe(μ-SCH 3)(μ-SH)Fe(CO)3 (Fesu
CHEMISTRY OF μ-DITHIOBIS(TRICARBONYLIRON), AN INORGANIC MIMIC OF ORGANIC DISULFIDES II. NUCLEOPHILIC S-S BOND CLEAVAGE BY ORGANOLITHIUM AND ORGANOMAGNESIUM REAGENTS
Seyferth, Dietmar,Henderson, Richard S.,Song, Li-Cheng,Womack, Gary B.
, p. 9 - 18 (2007/10/02)
Organolithium and Grignard reagents cleave the S-S bond of (μ-S2)Fe2(CO)6 at -78 deg C to give intermediates of type (μ-RS)(μMS)Fe2(CO)6 (M= Li or MgX).These may be alkylated with organic halides to produce complexes of type (μ-RS)(μ-R'S)Fe2(CO)6 and prot
