102919-04-0

Basic information

• Product Name: benzyl 2,3-O-isopropylidene-α-D-lyxo-pentodialdo-1,4-furanoside
• CAS NO: 102919-04-0
• Molecular Weight: 278.305
• Mol File: 102919-04-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: benzyl 2,3-O-isopropylidene-α-D-lyxo-pentodialdo-1,4-furanoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 2,3-O-isopropylidene-α-D-lyxo-pentodialdo-1,4-furanoside(102919-04-0)
• EPA Substance Registry System: benzyl 2,3-O-isopropylidene-α-D-lyxo-pentodialdo-1,4-furanoside(102919-04-0)

Safety Data

• Hazardous Substances Data: 102919-04-0(Hazardous Substances Data)

Upstream product

• 530-26-7 D-Mannose 
• 7757-38-2 2,3,5,6-di-O-isopropylidene-D-mannofuranose 
• 100-39-0 benzyl bromide 
• 54469-08-8 phenylmethyl 2,3:5,6-di-O-(1-methylethylidene)-α-D-mannofuranoside 
• 937020-97-8 benzyl 2,3-O-isopropylidene-α-D-mannofuranoside 
• 74912-02-0 1-O-benzyl-2,3-O-isopropylidene-α-D-manno-furanose 
• 14131-84-1 2,3:5,6-di-O-isopropylidene-α-D-mannofuranose 

Downstream Products

• 136994-75-7 (E)-3-((3aS,4R,6S,6aS)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-(diethoxy-phosphoryl)-acrylic acid ethyl ester 
• 96150-84-4 (3aR,4S,6S,6aS)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole-4-carboxylic acid 
• 1402155-11-6 1-O-benzyl-5-amino-5-cyano-5-deoxy-2,3-O-(1-methylethylidene)-β-L-erythro-pentofuranose 
• 1402155-10-5 1-O-benzyl-5-butylamino-5-cyano-5-deoxy-2,3-O-(1-methylethylidene)-β-L-erythro-pentofuranose 
• 1402155-09-2 1-O-benzyl-5-benzylamino-5-cyano-5-deoxy-2,3-O-(1-methylethylidene)-β-L-erythro-pentofuranose 
• 1402155-06-9 C₁₆H₂₀N₂O₃ 
• 1402155-07-0 C₁₇H₂₃NO₄ 
• 1402155-08-1 C₁₈H₂₂N₂O₄ 
• 1402222-23-4 (3R,5R)-1-benzyl-3,4,5-trihydroxy-piperidine 

Relevant articles and documents

An efficient and green oxidation of vicinal diols to aldehydes using polymer-supported (diacetoxyiodo)benzene as the oxidant

An operationally simple and clean oxidation of a variety of vicinal diols to aldehydes using polymer-supported (diacetoxyiodo)benzene (PSDIB) has been developed in high to excellent yields. Protecting groups such as OAc, OR, OBn, OBz and isopropylidene in the substrates were found to be stable under these reaction conditions. The regenerated PSDIB could be reused for the same reaction, affording oxidation products in high yield and purity. Georg Thieme Verlag Stuttgart.

Stereoselective syntheses of polyhydroxylated azepane derivatives from sugar-based epoxyamides. Part 1: Synthesis from d-mannose

An approach to the synthesis of polyhydroxyazepane derivatives from sugar-based epoxyamides or epoxyalcohols, in which the total regioselective epoxide opening by nitrogen nucleophiles is the key step, is described. Thus, novel polyhydroxyazepane carboxamides and aminomethyl polyhydroxyazepanes, with potential pharmacological interest, are synthesized from diacetone d-mannose. Configurational assignments of the obtained products were determined.

Chemoenzymatic synthesis of [3,9-13C]-labeled NeuAc and KDN

The chemoenzymatic synthesis of 13C-labeled sialic acid (NeuAc) and 3-deoxy-D-glycero-D-galacto-2-nonulosonic acid (KDN) as useful molecular probes for studying the conformation of sialyl or KDN oligosaccharides attached to proteins was perform