102956-79-6Relevant articles and documents
Regioselective C-H alkylation of anisoles with olefins catalyzed by cationic half-sandwich rare earth alkyl complexes
Oyamada, Juzo,Hou, Zhaomin
supporting information, p. 12828 - 12832 (2013/02/22)
A half sandwich helping: Cationic rare-earth alkyl species generated from half-sandwich rare-earth dialkyl complexes and [Ph3C][B(C 6F5)4] can serve as unique catalysts for the C-H regioselective alkylation of anisoles with alkenes. The reaction affords either ortho-monoalkylated derivatives or products substituted at the benzylic position, depending on the substrate chosen. Copyright