102969-07-3

Basic information

• Product Name: 2-(2-Methoxy-5,5-dimethyl-2λ⁵-[1,3,2]dioxaphosphinan-2-ylidene)-3-[(E)-phenylimino]-succinic acid dimethyl ester
• CAS NO: 102969-07-3
• Molecular Weight: 397.365
• Mol File: 102969-07-3.mol

Chemical Properties

• CAS DataBase Reference: 2-(2-Methoxy-5,5-dimethyl-2λ⁵-[1,3,2]dioxaphosphinan-2-ylidene)-3-[(E)-phenylimino]-succinic acid dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-Methoxy-5,5-dimethyl-2λ⁵-[1,3,2]dioxaphosphinan-2-ylidene)-3-[(E)-phenylimino]-succinic acid dimethyl ester(102969-07-3)
• EPA Substance Registry System: 2-(2-Methoxy-5,5-dimethyl-2λ⁵-[1,3,2]dioxaphosphinan-2-ylidene)-3-[(E)-phenylimino]-succinic acid dimethyl ester(102969-07-3)

Safety Data

• Hazardous Substances Data: 102969-07-3(Hazardous Substances Data)

Upstream product

• 622-37-7 Phenyl azide 
• 1005-69-2 2-methoxy-5,5-dimethyl-1,3,2-dioxaphosphorinane 
• 102969-01-7 2-methoxy-2-N-phenylimino-5,5-dimethyl-1,3,2-dioxaphosphorinane 
• 762-42-5 dimethyl acetylenedicarboxylate 

Downstream Products

• 102969-26-6 10-Methoxy-3,3-dimethyl-7-phenyl-1,5-dioxa-7-aza-6λ⁵-phospha-spiro[5.5]undeca-6(11),8-diene-8,9,10,11-tetracarboxylic acid tetramethyl ester 
• 102969-25-5 6-Methoxy-3,3-dimethyl-7-phenyl-1,5-dioxa-7-aza-6λ⁵-phospha-spiro[5.5]undeca-8,10-diene-8,9,10,11-tetracarboxylic acid tetramethyl ester 

Relevant articles and documents

Reactions de tris(alcoxy)iminophosphanes avec l'acetylene dicarboxylate de methyle: ylure, phosphonate et phosphorane

The tris(alkoxy) N-phenyl iminophosphanes react under mild conditions with acetylenic carboxylates to give phosphorus ylides with a β carbonyl group.These compounds, well characterized in the reaction mixture, have not been isolated.They are highly reactive and depending on the nature of substituents on phosphorus atom; give phosphonates, phosphoranes and cyclic ylides.