102969-22-2Relevant academic research and scientific papers
Reactions de tris(alcoxy)iminophosphanes avec l'acetylene dicarboxylate de methyle: ylure, phosphonate et phosphorane
Bellan, Jacques,Sanchez, Michel,Marre-Mazieres, Marie-Rose,Murillo Beltran, Arturo
, p. 491 - 495 (2007/10/02)
The tris(alkoxy) N-phenyl iminophosphanes react under mild conditions with acetylenic carboxylates to give phosphorus ylides with a β carbonyl group.These compounds, well characterized in the reaction mixture, have not been isolated.They are highly reactive and depending on the nature of substituents on phosphorus atom; give phosphonates, phosphoranes and cyclic ylides.
