7077-62-5

Upstream product

• 121-45-9 phosphorous acid trimethyl ester 
• 622-37-7 Phenyl azide 

Downstream Products

• 102969-21-1 2,2,2-Trimethoxy-1-phenyl-1,2-dihydro-2λ⁵-[1,2]azaphosphinine-3,4,5,6-tetracarboxylic acid tetramethyl ester 
• 102969-22-2 2,2,4-Trimethoxy-1-phenyl-1,4-dihydro-2λ⁵-[1,2]azaphosphinine-3,4,5,6-tetracarboxylic acid tetramethyl ester 
• 7006-95-3 O,O-dimethyl-N-methyl-N-phenyl-phosphoramidate 
• 102969-04-0 C₁₅H₂₀NO₇P 
• 133827-76-6 O,O-dimethyl N,N-deuteromethyl phenylamidophosphate 
• 133827-75-5 O,O-dideuteromethyl N,N-methylphenylamidophosphate 
• 133827-74-4 C₉H₅⁽²⁾H₉NO₃P 
• 58046-12-1 dimethyl N-phenyl-phosphoramidate 

Relevant academic research and scientific papers

Reactions de tris(alcoxy)iminophosphanes avec l'acetylene dicarboxylate de methyle: ylure, phosphonate et phosphorane

The tris(alkoxy) N-phenyl iminophosphanes react under mild conditions with acetylenic carboxylates to give phosphorus ylides with a β carbonyl group.These compounds, well characterized in the reaction mixture, have not been isolated.They are highly reactive and depending on the nature of substituents on phosphorus atom; give phosphonates, phosphoranes and cyclic ylides.

INDUCTIVE AND STERIC EFFECTS IN THE STAUDINGER REACTION

The sterically unhindered mode of the electrophilic addition of phenyl azide to trivalent phosphorus compounds and the inductive control in this initial step of the Staudinger reaction have been observed and discussed.

A nitrogen-15 nuclear magnetic resonance study of N-aryl phosphoramidates and phosphorimidates

15N nuclear magnetic resonance chemical shifts and one-bond 15N-31P couplings are reported for a series of five N-arylphosphoramidates and four N-arylphosphorimidates.Results are interpreted in terms of an extensively delocalized N lone pair in the phosphoramidates, with p?-p? donation into the aromatic ring being dominant over p?-d? donation from nitrogen to phosphorus.