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• 18399-62-7 W(CO)5(PPh2H) 
• 201595-93-9 (C₂H₅)4N⁽¹⁺⁾*(CO)5W(P(C₆H₅)2C(S)NC₆H₅)^(1-)=[(C₂H₅)4N][(CO)5W(P(C₆H₅)2C(S)NC₆H₅)] 
• 201595-95-1 [Et4N][W(CO)4(η(2)-PPh2C(=NPh)S)] 
• 201595-97-3 (CO)5W(P(C₆H₅)2C(NC₆H₅)SCH₂CN) 
• 14586-49-3 (pyridine)pentacarbonyltungsten⁽⁰⁾ 
• 155145-00-9 W(CO)5(P(C₆H₅)2(CS₂C₂HNH₂))⁽¹⁺⁾*BF₄^(1-)=[W(CO)5(P(C₆H₅)2(CS₂C₂HNH₂))]BF₄ 
• 429-41-4 tetrabutyl ammonium fluoride 
• 201596-09-0 (CO)5W(P(C₆H₅)2C₃H₁NS(NH₂)C₆H₅)⁽¹⁺⁾*BF₄^(1-)=[(CO)5W(P(C₆H₅)2C₃HNS(NH₂)C₆H₅)]BF₄ 

Relevant academic research and scientific papers

Syntheses and crystal structures of tungsten complexes with various ligands containing (1,3-dithioliumyl)diphenylphosphine

The (dithioalkylcarbonyl)diphenylphosphinotungsten complexes W(CO)5[PPh2(CS2R)] (2-5) (R = CH2C≡CH; CH2C≡CD; CH2C≡N; CH(CH3)C≡N) are accessible by the alkylation reactions of the

Syntheses and crystal structures of tungsten complexes containing various (thiazoliumyl)diphenylphosphine ligands

Alkylation reactions at the S atom of the anionic PPh2C(=NPh)S- ligand coordinated to a tungsten pentacarbonyl group afford the neutral complexes W(CO)5PPh2C(=NPh)SR (4, R = CH2C≡CH; 5, R = CH2C≡N; 6, R = CH2CONH2; 7, R = CH2CH=CH2; 8, R = CH2CO2-Me). Protonation of 4 with HBF4 at room temperature causes cyclization to the cationic complex W(CO)5PPh2[CSCH2C(CH2)NPh]BF 4 (10), which contains a (thiazoliumyl)diphenylphosphine ligand. Similarly, protonation reactions of 5 and 6 with HBF4 give the cationic complex [W(CO)5PPh2CSCHC(NH2)NPh]BF4 (11) and the neutral complex W(CO)5PPh2CSCHC-(OBF3)NPh (12), respectively, both of which contain (thiazoliumyl)diphenylphosphine ligands. The structures of 10 and 12 are determined by X-ray diffraction analyses.

Reactions of Coordinated Ligands, XV. Ligand Properties of Complexes of Lithium Organophosphides (CO)nM(RR'PLi)m (M = Ni, Cr, Mo, W; n = 3, 4, 5; m = 1, 2) - Crystal and Molecular Structure of (-)(+)

Complexes of lithium organophosphides (CO)nM(RR'PLi)m obtained by deprotonation of the corresponding phosphine complexes (CO)nM(RR'PH)m are monodentate or bidentate ligands forming anionic binuclear complexes of the type (-) (A) or (2-) which may be isolated as (+) salts.Oxidation of the anions (2-) with 1,2-dibromoethane affords the neutral phosphido complexes (CO)4Mo(RR'P)Mo(CO)4 with reactive PH functional groups.The crystal and molecular structure of (-)(+) shows a distorted tetrahedral geometry at the central P atom of the complex anion.The Mo-P bond is unusual long (2.636(1) Angstroem), the phosphorus atom showing a pronounced trans effect on Mo-C bond lengths ((Mo-C)av. trans P 1.975(5) Angstroem, (Mo-C)av. cis P 2.043(6) (Mo(1)) or 2.038(6) Angstroem (Mo(2)), respectively). - Key words: Complexes of Lithium Organophosphides, Formation of Binuclear Complexes, Ligand Exchange, Oxidation