1029982-63-5Relevant academic research and scientific papers
Synthesis and characterization of titanium tetraisocyanide complexes, [CpTi(CNXyl)4E], E = I, SnPh3, and SnMe3
Allen, Jessica M.,Ellis, John E.
, p. 1536 - 1542 (2008/09/18)
Oxidation of [CpTi(CO)4]- by I2, Ph3SnCl, and Me3SnCl in the presence of four equivalents of CNXyl, Xyl = 2,6-dimethylphenyl, affords unprecedented titanium tetraisocyanide complexes, [CpTi(CNXyl)4E], E = I, SnPh3, SnMe3. These have been isolated and characterized by spectroscopic methods as well as single-crystal X-ray crystallography. A by-product of the iodine reaction was the Ti(III) complex, [CpTi(CNXyl)2I2], which was also characterized by X-ray crystallography.
