103012-26-6

Usage

Uses

3-Phenyl-9H-carbazole is a useful research chemical.

Chemical Properties

off-white powder

Upstream product

• 108993-46-0 3-diazo-3H-carbazole 
• 71-43-2 benzene 
• 32228-99-2 4-phenyldiphenylamine 
• 2788-23-0 9-nitroso-9H-carbazole 
• 14221-01-3 tetrakis(triphenylphosphine) palladium⁽⁰⁾ 
• 1592-95-6 3-bromo-9H-carbazole 
• 96042-30-7 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran 
• 98-80-6 phenylboronic acid 
• 4894-75-1 1-phenyl-4-cyclohexanone 
• 59-88-1 phenylhydrazine hydrochloride 
• 76129-25-4 2-amino-m-terphenyl 
• 61-54-1 tryptamine 
• 41738-70-9 3-bromo-[1,1'-biphenyl]-4-amine 
• 63344-48-9 [1,1':3',1-terphenyl]-4'-amine 

Downstream Products

• 1218786-27-6 CzPAP 
• 1028648-09-0 3,9-diphenyl-9H-carbazole 

Relevant academic research and scientific papers

Rh(I)-catalyzed decarbonylation synthesis of carbazoles via C-N cleavage

A one-pot Rh(I)-catalyzed synthesis of 9-H carbazoles via C-N bond cleavage by activation of aldehyde C-H bonds is reported. This protocol offers good yields and tolerates a broad range of functional groups. Based on the extensive control experiments, we propose a plausible decarbonylation mechanism.

A strategy to construct multifunctional TADF materials for deep blue and high efficiency yellow fluorescent devices

Three deep blue thermally activated delayed fluorescence (TADF) molecules are designed by connecting three different sterically hindered electron-donating groups with 2,6-diphenylpyrimidine acceptors. The rigid structures based on carbazole derivatives en

Carbazole synthesis by platinum-catalyzed C-H functionalizing reaction using water as reoxidizing reagent

Treatment of 1-aminobiphenyl and diphenylamine with catalytic amount of Pt/C in hydrothermal water (250 °C, 4 MPa) affords 9H-carbazole in good yield. In this catalytic cycle, water works as reoxidizing reagent for platinum catalyst. Copyright

One-pot synthesis of carbazoles from cyclohexanones and arylhydrazine hydrochlorides under metal-free conditions

One-pot synthesis of carbazoles from cyclohexanones and arylhydrazine hydrochlorides is disclosed. Various substituted carbazoles were obtained in moderate to good yields via a sequence of condensation, cyclization and dehydrogenation under metal free conditions using molecular oxygen as an oxidant.

Synthesis of Carbazoles by a Diverted Bischler-Napieralski Cascade Reaction

An unforeseen twist in a seemingly trivial Bischler-Napieralski reaction led to the selective formation of an unexpected carbazole product. The reaction proved to be general, providing access to a range of diversely substituted carbazoles from readily available substrates. Judicious variation of substituents revealed a complex cascade mechanism comprising no less than 10 elementary steps, that could be diverted in multiple ways toward various other carbazole derivatives.

A novel bipolar host material based on carbazole and 1,3,5-triazine with an extremely low efficiency roll-off for green PhOLEDs

In this contribution, a novel bipolar host material, namely CzTrz, consisting of a phenylcarbazole for hole transport and a diphenyltriazine for electron transport, was synthesized and investigated. Besides, a carbazole-based unipolar host BCz2 was designed as a reference. Both CzTrz and BCz2 display good thermal stability, high triplet energy level (ET) and suitable frontier orbital levels. Green PhOLEDs hosted by CzTrz and BCz2 show turn-on voltage (Von) of 3.5 and 3.8 V, maximum luminance (Lmax) of 30,280 and 35,050 cd m?2, and maximum external quantum efficiency (EQEmax) of 15.49 and 11.84%, respectively. Remarkably, the CzTrz-based device reveals an extremely low efficiency roll-off at the high luminance, for example, 15.35% at 1000 cd m?2 and 13.85% at 5000 cd m?2, corresponding to merely 0.9% and 10.6% roll-off percentage, which is among the best results ever reported as green bipolar hosts.

COMPOUND FOR ORGANIC OPTOELECTRONIC DEVICE, COMPOSITION FOR ORGANIC OPTOELECTRONIC DEVICE, ORGANIC OPTOELECTRONIC DEVICE, AND DISPLAY DEVICE

The present invention relates to a compound for an organic optoelectronic device, represented by Chemical Formula 1; a composition for an organic optoelectronic device, including same; an organic optoelectronic device; and a display device. The description of Chemical Formula 1 is the same as that defined in the specification.

COMPOUND FOR ORGANIC OPTOELECTRONIC DEVICE, COMPOSITION FOR ORGANIC OPTOELECTRONIC DEVICE AND ORGANIC OPTOELECTRONIC DEVICE AND DISPLAY DEVICE

The present specification relates to a compound for an organic optoelectronic device represented by chemical formula 1, a composition for an organic optoelectronic device including the same, an organic optoelectronic device, and a display device. Details

COMPOSITION FOR OPTOELECTRONIC DEVICE AND ORGANIC OPTOELECTRONIC DEVICE AND DISPLAY DEVICE

A composition for an organic optoelectronic device, an organic optoelectronic device, and a display device, the composition including a first compound; a second compound; and a third compound, the first compound, the second compound, and the third compoun

Concatenating Suzuki Arylation and Buchwald–Hartwig Amination by A Sequentially Pd-Catalyzed One-Pot Process—Consecutive Three-Component Synthesis of C,N-Diarylated Heterocycles

The concatenation of Suzuki coupling and Buchwald-Hartwig amination in a consecutive multicomponent reaction opens a concise, modular and efficient one-pot approach to diversely functionalized heterocycles, as exemplified for 3,10-diaryl 10H-phenothiazines, 3,9-diaryl 9H-carbazoles, and 1,5-diaryl 1H-indoles, in high yields starting from simple staring materials. Moreover, this one-pot reaction is a sequentially palladium-catalyzed process that does not require additional catalyst loading after the first coupling step.