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N-Phenyl-4-biphenylamine, with the chemical abstracts service number 32228-99-2, is an organic compound that serves as a crucial reagent in the synthesis of heterocyclic compounds. These heterocyclic compounds are integral to the development of organic electrical devices, making N-Phenyl-4-biphenylamine a significant component in the advancement of modern electronic technology.

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  • 32228-99-2 Structure
  • Basic information

    1. Product Name: N-PHENYL-4-BIPHENYLAMINE
    2. Synonyms: 4-ANILINOBIPHENYL;N-PHENYL-4-BIPHENYLAMINE;N-Phenyl-biphenyl-4-aMine;N-(4-Biphenylyl)-N-phenylamine;4-(Phenylamino)-1,1'-biphenyl;4-Phenyldiphenylamine;Biphenyl-4-ylphenylamine;N-(1,1'-Biphenyl-4-yl)-N-phenylamine
    3. CAS NO:32228-99-2
    4. Molecular Formula: C18H15N
    5. Molecular Weight: 245.32
    6. EINECS: 202-303-5
    7. Product Categories: N/A
    8. Mol File: 32228-99-2.mol
  • Chemical Properties

    1. Melting Point: 113 °C
    2. Boiling Point: 411.2 °C at 760 mmHg
    3. Flash Point: 217.6 °C
    4. Appearance: /Solid
    5. Density: 1.111
    6. Vapor Pressure: 5.68E-07mmHg at 25°C
    7. Refractive Index: 1.646
    8. Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
    9. Solubility: DMSO (Slightly), Methanol (Slightly)
    10. PKA: 0.73±0.20(Predicted)
    11. Sensitive: Air Sensitive
    12. CAS DataBase Reference: N-PHENYL-4-BIPHENYLAMINE(CAS DataBase Reference)
    13. NIST Chemistry Reference: N-PHENYL-4-BIPHENYLAMINE(32228-99-2)
    14. EPA Substance Registry System: N-PHENYL-4-BIPHENYLAMINE(32228-99-2)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 32228-99-2(Hazardous Substances Data)

32228-99-2 Usage

Uses

Used in Organic Electrical Device Industry:
N-Phenyl-4-biphenylamine is used as a reagent for the preparation of heterocyclic compounds, which are essential in the development and functioning of organic electrical devices. Its role in the synthesis process is pivotal for creating the complex molecular structures that enable these devices to perform their intended functions efficiently.

Check Digit Verification of cas no

The CAS Registry Mumber 32228-99-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,2,2 and 8 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 32228-99:
(7*3)+(6*2)+(5*2)+(4*2)+(3*8)+(2*9)+(1*9)=102
102 % 10 = 2
So 32228-99-2 is a valid CAS Registry Number.
InChI:InChI=1/C18H15N/c1-3-7-15(8-4-1)16-11-13-18(14-12-16)19-17-9-5-2-6-10-17/h1-14,19H

32228-99-2 Well-known Company Product Price

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  • Alfa Aesar

  • (H64808)  4-(Phenylamino)biphenyl, 98%   

  • 32228-99-2

  • 250mg

  • 245.0CNY

  • Detail
  • Alfa Aesar

  • (H64808)  4-(Phenylamino)biphenyl, 98%   

  • 32228-99-2

  • 1g

  • 735.0CNY

  • Detail
  • Alfa Aesar

  • (H64808)  4-(Phenylamino)biphenyl, 98%   

  • 32228-99-2

  • 5g

  • 2940.0CNY

  • Detail

32228-99-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name N,4-diphenylaniline

1.2 Other means of identification

Product number -
Other names N-phenyl-bis(4-biphenyl)amine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:32228-99-2 SDS

32228-99-2Relevant articles and documents

Organic compound and electronic device and device containing the same

-

Paragraph 0230; 0257-0259, (2021/09/11)

The invention relates to the technical field of organic electroluminescent materials, in particular to an organic electroluminescent material 9 with 10 -9 dihydro 9 -10 -dimethyl and oxanthrene and arylamine groups, an electronic device containing the compound and a device. The organic electroluminescent device has lower driving voltage. Higher luminous efficiency and longer service life.

Organic compound, electronic component, comprising same and electronic device

-

Paragraph 0116; 0165-0168; 0173, (2021/07/17)

The invention provides an organic compound, an electronic component comprising the same and an electronic device, and belongs to the technical field of organic electroluminescence. The compound provided by the invention contains condensed rings of carbazole and fluorene, dibenzofuran or dibenzothiophene, has a rigid plane structure and high light-emitting quantum efficiency, and can improve the thermal stability and film stability of a material. According to the invention, the low triplet state energy level is effectively improved; and the compound is used for a light-emitting layer in a red light device, can effectively improve non-uniformity of charge transmission, improves the light-emitting efficiency and stability of the device, and effectively improves the performance of the device.

COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF

-

Paragraph 0103; 0106-0109, (2021/06/22)

In the present invention, provided is a novel compound capable of improving luminance efficiency, stability, and service life of an element, an organic electronic element using the same, and an electronic device thereof. By using the compound of the present invention, high luminance efficiency, low driving voltages, and high heat resistance of the element can be achieved, and color purity and service life of the element can be greatly improved.

Arylamine derivative taking carbazole as core and application thereof

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Paragraph 0063-0065; 0069, (2021/10/30)

The invention relates to an arylamine derivative taking carbazole as a core and application thereof, belongs to the technical field of semiconductors and provides a compound structure as shown in a general formula (I). The invention further discloses application of the compound. The compound provided by the invention has a strong electron blocking effect, and the recombination efficiency of excitons in the light-emitting layer is improved. When used as a luminescent functional layer material OLED, the branched chain in the scope of the invention can effectively improve the utilization rate of excitons and the radiation efficiency.

Organic light-emitting auxiliary layer material, preparation method and application thereof, and organic electroluminescent device

-

Paragraph 0055-0058, (2021/06/21)

The invention discloses an organic light-emitting auxiliary layer material, a preparation method and application thereof, and an organic electroluminescent device, and relates to the field of organic photoelectric materials. The chemical structural formula of the organic light-emitting auxiliary layer material is shown in the specification, wherein R1, R2, R3 and R4 are independently selected from hydrogen, deuterium, halogen, cyano, substituted or non-substituted alkyl, substituted or non-substituted aryl, substituted or non-substituted heteroaryl and a substituted or non-substituted fused ring group, and Ar1 and Ar2 are respectively and independently selected from a substituted or unsubstituted aryl group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted fused ring group and a substituted or unsubstituted spiro group. The organic light-emitting auxiliary layer material has efficient electron blocking capability and hole transport capability, a device prepared from the organic light-emitting auxiliary layer material has high light-emitting efficiency, low driving voltage and high heat resistance, the color purity of the device can be improved, and the service life of the device can be prolonged. The organic light-emitting auxiliary layer material can be widely applied to organic electroluminescent devices.

Nickel-Catalyzed Amination of Aryl Nitriles for Accessing Diarylamines through C?CN Bond Activation

Wu, Ke,Rong, Qiang,Sun, Nan,Hu, Baoxiang,Shen, Zhenlu,Jin, Liqun,Hu, Xinquan

, p. 4708 - 4713 (2021/08/27)

A nickel-catalyzed amination to access diarylamines has been developed through C?CN bond activation of aryl nitriles with anilines. In this developed catalytic protocol, various aromatic and heteroaromatic nitriles could be utilized as the electrophiles to couple with substituted anilines. A diversity of diarylamines were obtained in 15–95% yields. (Figure presented.).

Organic compound, electronic device comprising organic compound and electronic equipment

-

Paragraph 0116-0118, (2021/08/07)

The invention relates to an organic compound, an electronic device comprising the organic compound, and electronic equipment comprising the electronic device. The structural formula of the organic compound is represented by a chemical formula 1, and the organic compound is applied to the electronic device and can significantly improve the performance of the electronic device.

Organic compound and electronic component and electronic device comprising same

-

Paragraph 0113-0115, (2021/07/17)

The invention provides an organic compound and an electronic element and an electronic device comprising the same, and belongs to the technical field of organic electroluminescence. The structural formula of the organic compound is composed of a structure as shown in a chemical formula 1, and the organic compound has excellent photoelectric properties, can improve the luminous efficiency and the service life of the device, and can reduce the working voltage.

Organic compound, and electronic element and electronic device using same

-

Paragraph 0150-0151, (2021/07/14)

The invention relates to an organic compound. The structure of the organic compound is shown as a formula I. When the organic compound is used as a hole adjustment layer material of an electronic element, driving voltage can be reduced, the luminous efficiency of a device can be improved, and the service life of the device can be prolonged.

Mediator-Enabled Electrocatalysis with Ligandless Copper for Anaerobic Chan-Lam Coupling Reactions

Walker, Benjamin R.,Manabe, Shuhei,Brusoe, Andrew T.,Sevov, Christo S.

supporting information, p. 6257 - 6265 (2021/05/07)

Simple copper salts serve as catalysts to effect C-X bond-forming reactions in some of the most utilized transformations in synthesis, including the oxidative coupling of aryl boronic acids and amines. However, these Chan-Lam coupling reactions have historically relied on chemical oxidants that limit their applicability beyond small-scale synthesis. Despite the success of replacing strong chemical oxidants with electrochemistry for a variety of metal-catalyzed processes, electrooxidative reactions with ligandless copper catalysts are plagued by slow electron-transfer kinetics, irreversible copper plating, and competitive substrate oxidation. Herein, we report the implementation of substoichiometric quantities of redox mediators to address limitations to Cu-catalyzed electrosynthesis. Mechanistic studies reveal that mediators serve multiple roles by (i) rapidly oxidizing low-valent Cu intermediates, (ii) stripping Cu metal from the cathode to regenerate the catalyst and reveal the active Pt surface for proton reduction, and (iii) providing anodic overcharge protection to prevent substrate oxidation. This strategy is applied to Chan-Lam coupling of aryl-, heteroaryl-, and alkylamines with arylboronic acids in the absence of chemical oxidants. Couplings under these electrochemical conditions occur with higher yields and shorter reaction times than conventional reactions in air and provide complementary substrate reactivity.

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