103040-77-3Relevant academic research and scientific papers
PHOTOLYSIS OF QUINOLYL AND ISOQUINOLYL AZIDES IN ALCOHOLS CONTAINING SULFURIC ACID
Sawanishi, Hiroyuki,Hirai, Toyoko,Tsuchiya, Takashi
, p. 2071 - 2074 (2007/10/02)
Photolysis of 3-azidoquinoline, 4-azidoisoquinoline, and 4-azidoquinoline N-oxide in alcohols containing sulfuric acid gave the corresponding α-alkoxy amino compounds (2,3,5,7) via nitrenium ion intermediates.In contrast, 3-azidoquinoline N-oxide, 5-azido and 8-azidoquinoline, and 5-azidoquinoline, upon irradiation under similar conditions, gave the different type of α-alkoxy amino compounds such as 9 and 13 via azirine or azacycloheptatetraene intermediates.
