103056-74-2Relevant academic research and scientific papers
Synthesis of cyclopent-2-enones from furans using a nebulizer-based continuous flow photoreactor
Ioannou, Georgios I.,Montagnon, Tamsyn,Kalaitzakis, Dimitris,Pergantis, Spiros A.,Vassilikogiannakis, Georgios
supporting information, p. 10151 - 10155 (2017/12/26)
A series of hydroxycyclopent-2-enones and methoxycyclopent-2-enones have been synthesized in a single operation from simple furan substrates using an innovative continuous flow nebulizer system (NebPhotOX). Photooxygenation of the furan substrates takes place in an aerosol within the NebPhotOX system.
One-pot transformation of simple furans into 4-Hydroxy-2-cyclopentenones in water
Kalaitzakis, Dimitris,Triantafyllakis, Myron,Alexopoulou, Ioanna,Sofiadis, Manolis,Vassilikogiannakis, Georgios
supporting information, p. 13201 - 13205 (2015/02/19)
A highly efficient one-pot transformation of readily accessible furans into 4-hydroxy-2-cyclopentenones in H2O, using singlet oxygen as oxidant, has been developed.
Enantioselective synthesis of cyclopentenones via rhodium-catalyzed kinetic resolution and desymmetrization of 4-alkynals
Tanaka, Ken,Fu, Gregory C.
, p. 10296 - 10297 (2007/10/03)
We have developed two new catalytic processes that provide efficient access to interesting chiral building blocks, cyclopentenones that bear tertiary and quaternary stereocenters, in high enantiomeric excess and very good yield. Structures such as these h
A NEW SYNTHESIS OF 4-METHOXY-CYCLOPENT-2-EN-1-ONES
Scettri, Arrigo
, p. 5141 - 5144 (2007/10/02)
4-methoxy-cyclopent-2-en-1-ones 6 are easily obtained through a simple procedure involving in the key-step the conversion of 2-furylcarbinols 1 into 1,1,2-trimethoxy-alkan-4-ones 3, a masked form of 1,4-dicarbonil compounds, by treatment with Amberlyst H15 in methanolic solution.Then, the regeneration of the aldehydic function and a base-catalysed aldolic condensation lead in high yields to the finalproducts 6.
