103077-83-4Relevant articles and documents
Regioselective Generation and Diastereoselective Reactions in the β-Position of Nitro Groups of Secondary Nitroalkanes through α,β-Doubly Deprotonated Derivatives (Super-enamines)
Braendli, Urs,Eyer, Martin,Seebach, Dieter
, p. 575 - 588 (2007/10/02)
Open-chain (2-nitropropane, -butane, -pentane, -hexane) and cyclic (nitrocyclopentane, -hexane) secondary nitroalkanes (1) were doubly deprotonated with one equivalent each of n- and t-butyllithium in THF/HMPT or DMPU.Bis(lithiooxy)enamines (2, dianion de