1030871-49-8

Basic information

• Product Name: C₁₈H₂₇ClN₂O
• Synonyms: C₁₈H₂₇ClN₂O
• CAS NO: 1030871-49-8
• Molecular Weight: 322.878
• Mol File: 1030871-49-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₈H₂₇ClN₂O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₂₇ClN₂O(1030871-49-8)
• EPA Substance Registry System: C₁₈H₂₇ClN₂O(1030871-49-8)

Safety Data

• Hazardous Substances Data: 1030871-49-8(Hazardous Substances Data)

Upstream product

• 116407-32-0 (1R,2R)-(-)-1,2-diammoniumcyclohexane mono-L-(+)-tartrate 
• 183017-88-1 3-tert-butyl-5-(chloromethyl)-2-hydroxybenzaldehyde 

Relevant articles and documents

Ionic liquid-functionalized salen Mn(III) complexes as tunable separation catalysts for enantioselective epoxidation of styrene

A series of novel chiral salen Mn(III) complexes functionalized by ionic liquid (IL) of 1-propylamine-3-methylimidazolium tetrafluoroborate were synthesized through the reaction of amino group ({single bond}NH2) of the IL with chloromethyl ({single bond}CH2Cl) in the salen ligand at one side of the 5 position (complex 2) and at two sides of the 5, 5′ position (complex 3), as well as by direct axial coordination between {single bond}NH2 of the IL and metal center of the salen Mn(III) complex (complex 4). All of the synthesized complexes were well characterized, and their performance in the enantioselective epoxidation of styrene was investigated systematically. Under optimum reaction conditions, a 99% styrene epoxide yield with 50% enantiometric excess (ee) could be obtained over the complex 2. Furthermore, the IL-functionalized chiral salen Mn(III) complexes of 2 and 3 could be conveniently separated from the reaction system by simple precipitation in hexane and subsequently used without significant loss of activity and enantioselectivity.