103108-54-9Relevant academic research and scientific papers
A FACILE COUPLING REACTION OF VINYL KETONES WITH ALDEHYDES CATALYZED BY RHODIUM(I) HYDRIDE COMPLEX
Sato, Susumu,Matsuda, Isamu,Izumi, Yusuke
, p. 1875 - 1878 (1985)
A convenient α-hydroxyalkylation of vinyl ketones is accomplished by the coupling reaction of vinyl ketone and aldehyde, where rhodium(I) enolate derived from HRh(PPh3)4 plays an important role in the carbon-carbon bond forming step.
Rhodium(I)- or ruthenium(II)-catalyzed direct coupling of vinyl ketones with aldehydes and the subsequent reduction to give aldol derivatives anti-selectively
Sato, Susumu,Matsuda, Isamu,Shibata, Masahiro
, p. 347 - 356 (2007/10/02)
A vinyl ketone reacts with an aldehyde to give an α-methylene-β-hydroxyalkanone with the concomitant formation of the vinyl ketone dimer in the presence of catalytic amount of RhH(PPh3)4 or RuH2(PPh3)4 under almost neutral conditions.The selectivity of th
