A FACILE COUPLING REACTION OF VINYL KETONES WITH ALDEHYDES CATALYZED BY RHODIUM(I) HYDRIDE COMPLEX

DOI: 10.1246/cl.1985.1875

Source and publish data:

Chemistry Letters p. 1875 - 1878 (1985)

Update date:2022-08-03

Topics:

Authors:

Sato, Susumu

Matsuda, Isamu

Izumi, Yusuke

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1985.1875

A convenient α-hydroxyalkylation of vinyl ketones is accomplished by the coupling reaction of vinyl ketone and aldehyde, where rhodium(I) enolate derived from HRh(PPh3)4 plays an important role in the carbon-carbon bond forming step.

Full text of DOI:10.1246/cl.1985.1875

Products guided by the article

Product name:1-Cyclohexyl-3-hydroxy-2-methylene-pentan-1-one

Cas No:103108-54-9

R&D Labs maybe for 103108-54-9

Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.
YORK CHEMICALS LTD

Contact:+1 (647) 918 5848

Address:2343 BRIMLEY RD., Suite 250
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
HANGZHOU ICH BIOFARM CO.,LTD

Contact:+86-571-28186845

Address:Room 1224,Eastcom Mansion,398 Wensan Road,Hangzhou,310013 China
Guangzhou Flower's Song Fine Chemical CO,. Ltd

Contact:+86-20-87475199

Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China

Relevant to this article

Doi:10.1002/oms.1210010203
(1968)
Synthesis of a precursor to quassimarin

Doi:10.1021/jo00367a017
(1986)
A Tactically Novel Alternative to Acyclic Stereoselection Based on the Concept of a Replicating Chiron - 1,3- and 1,4-C-Methyl Substitution

Doi:10.1016/S0040-4039(01)80904-7
(1985)
Reactivity of cationic triruthenium carbonyl clusters: From pyrimidinium ligands to N-heterocyclic carbenes

Doi:10.1021/om101130g
(2011)
Doi:10.1002/hlca.19550380136
(1955)
Doi:10.1021/ja01536a038
(1958)

Article Doi