A FACILE COUPLING REACTION OF VINYL KETONES WITH ALDEHYDES CATALYZED BY RHODIUM(I) HYDRIDE COMPLEX

DOI: 10.1246/cl.1985.1875

Source and publish data:

Chemistry Letters p. 1875 - 1878 (1985)

Update date:2022-08-03

Topics:

Authors:

Sato, Susumu

Matsuda, Isamu

Izumi, Yusuke

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Article abstract of DOI:10.1246/cl.1985.1875

A convenient α-hydroxyalkylation of vinyl ketones is accomplished by the coupling reaction of vinyl ketone and aldehyde, where rhodium(I) enolate derived from HRh(PPh3)4 plays an important role in the carbon-carbon bond forming step.

Full text of DOI:10.1246/cl.1985.1875

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