103126-14-3Relevant academic research and scientific papers
REACTIVITY AND CHEMOSELECTIVITY OF PRIMARY Z-β-ENAMINO-λ5 PHOSPHAZENES TOWARDS ELECTROPHILES
Barluenga, Jose,Lopez, Fernando,Palacios, Francisco,Cano, Felix H.,de la Concepcion Foces-Foces, Maria
, p. 2329 - 2334 (2007/10/02)
The multifunctional character of Z-β-enamino-λ5-phosphazenes (2) towards several electrophiles is shown.Thus, while hydrogen or alkyl halides react through the P=N double bond, affording β-enaminophosphonium salts (3) and (4), in the presence o
A FACILE AND EFFICIENT PREPARATION OF THE UNKNOWN PRIMARY β-ENAMINOPHOSPHINES. SYNTHESIS OF THE FIRST 1,3,4-DIAZA-λ5-PHOSPHININES.
Barluenga, Jose,Lopez, Fernando,Palacios, Francisco
, p. 2875 - 2878 (2007/10/02)
N-Arylphospha-λ5-azenes (1) and (3) were reduced with LiAlH4 to phosphine derivatives.The addition of ethyl azidoformate to β-enaminophosphine (4) followed by heating at 150 deg C yielded 1,3,4-diaza-λ5-phosphinine derivatives (8).
