103126-22-3Relevant academic research and scientific papers
Migration of the Methoxy Group in an Organosilicon Cation. Reactions of (Bromodiphenylsilyl)(methoxydimethylsilyl)bis(trimethylsilyl)methane with Silver Borofluoride and Silver Chloride. Crystal Structure of (Chlorodiphenylsilyl)(methoxydimethylsilyl)bis(
Buttrus, Nabeel H.,Eaborn, Colin,Hitchcock, Peter B.,Lickiss, Paul D.,Najim, Sabah T.
, p. 891 - 894 (2007/10/02)
The reaction of the bromide (Me3Si)2C(SiMe2OMe)(SiPh2Br) (1) with AgBF4 in Et2O is found to give a 4:1 mixture of the rearranged fluoride (Me3Si)2C(SiMe2F)(SiPh2OMe) and the unrearranged (Me3Si)2C(SiMe2OMe)(SiPh2F).The 1,3 Si-Si migration of the OMe group
