103126-24-5Relevant academic research and scientific papers
Migration of the Methoxy Group in an Organosilicon Cation. Reactions of (Bromodiphenylsilyl)(methoxydimethylsilyl)bis(trimethylsilyl)methane with Silver Borofluoride and Silver Chloride. Crystal Structure of (Chlorodiphenylsilyl)(methoxydimethylsilyl)bis(
Buttrus, Nabeel H.,Eaborn, Colin,Hitchcock, Peter B.,Lickiss, Paul D.,Najim, Sabah T.
, p. 891 - 894 (2007/10/02)
The reaction of the bromide (Me3Si)2C(SiMe2OMe)(SiPh2Br) (1) with AgBF4 in Et2O is found to give a 4:1 mixture of the rearranged fluoride (Me3Si)2C(SiMe2F)(SiPh2OMe) and the unrearranged (Me3Si)2C(SiMe2OMe)(SiPh2F).The 1,3 Si-Si migration of the OMe group
Unimolecular Alcoholysis of Organosilicon Halides of the Type (Me3Si)2C(SiMe2OMe)(SiR'2X). Anchimeric Assistance by and Migration of the OMe Group
Eaborn, Colin,Lickiss, Paul D.,Najim, Sabah T.,Romanelli, M. Novella
, p. 1754 - 1755 (2007/10/02)
The compound R2C(SiMe2OMe)(SiMe2Cl) (R = SiMe3 throughout) reacts more rapidly with CF3CH2OH than with MeOH, and R2C(SiMe2OMe) reacts with EtOH to give exclusively the rearranged product R2C(SiMe2OEt)(SiPh2OMe), indicating that the rate-determining step of the solvolyses involves formation of a methoxy-bridged cation; migration of the OMe group also occurs in the reaction of the bromide with AgBF4.
