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10314-89-3

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10314-89-3 Usage

Uses

Used in Pharmaceutical Industry:
Used in Research Applications:
In the field of research, (13α,17aα)-7-Acetyloxy-14β,15β:21,23-diepoxy-3β-hydroxy-4,4,8-trimethyl-D-homo-24-nor-17-oxa-5α-chola-20,22-dien-16-one serves as a valuable compound for studying the effects of its structure on biological systems. Researchers can use this compound to investigate its interactions with various biological targets and explore its potential applications in drug development.

Check Digit Verification of cas no

The CAS Registry Mumber 10314-89-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,3,1 and 4 respectively; the second part has 2 digits, 8 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 10314-89:
(7*1)+(6*0)+(5*3)+(4*1)+(3*4)+(2*8)+(1*9)=63
63 % 10 = 3
So 10314-89-3 is a valid CAS Registry Number.

10314-89-3Downstream Products

10314-89-3Relevant articles and documents

The Synthesis of a 1α,2α,3α-Triacetoxy Limonoid

Kehrli, Anne R. H.,Taylor, David A. H.,Niven, Margaret

, p. 2057 - 2065 (2007/10/02)

The report that Meerwein-Ponndorf reduction of gedunin (1a) gives 3α-hydroxy-3-deoxogedunin (2a) is wrong; the product is the 3β-epimer (2b). 3α-Acetoxy-7-deacetoxy-3-deoxo-7-oxgedunin (3c) was prepared by a stereospecific synthesis from cedrolide (1b), 7-deacetoxy-7-oxogedunin; osmium tetroxide oxidation then gave the 1,2α-glycol, isolated as the acetate (4a).Similarly, oxidation of the 3β-alcohol (3b) also gave the α-oriented glycol, as anticipated from the steric hindrance of the β-face of the molecule.Oxidation of the allylic alcohols (2b) or (3b), or of the allylic acetate (2d) with perbenzoic acid also takes place from the α-face of the molecule, giving the corresponding α-oxides (5a-c).The oxidation is pH sensitive; with a benzoate buffer the 7-oxo group in alcohol (3b) undergoes Baeyer-Villiger oxidation, giving the ε-lactone isolated as the acetate (6a).Opening of the oxide ring in the 3β,7α-diacetoxy oxide (5c) is complex.Identification of the products shows that the reaction involves participation by both the acetate groups.In contrast the 3β-acetoxy-7-oxo compound (5d) and the ε-lactone (6a) give the products of ring opening with assistance from the neighbouring acetate group, while the 3β-hydroxy compound (5b) gives the simple bromohydrin.

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