103164-24-5

Basic information

• Product Name: 1-naphthalenyl triphenylmethyl ketone
• CAS NO: 103164-24-5
• Molecular Weight: 398.504
• Mol File: 103164-24-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-naphthalenyl triphenylmethyl ketone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-naphthalenyl triphenylmethyl ketone(103164-24-5)
• EPA Substance Registry System: 1-naphthalenyl triphenylmethyl ketone(103164-24-5)

Safety Data

• Hazardous Substances Data: 103164-24-5(Hazardous Substances Data)

Upstream product

• 519-73-3 triphenylmethane 
• 879-18-5 naphthalene-1-carbonic acid chloride 
• 4303-71-3 triphenylmethyl sodium 

Downstream Products

• 103510-86-7 2,2,2-triphenyl-1-(2-phenyl-1,2-dihydro-[1]naphthyl)-ethanone 
• 630-95-5 1-naphthyldiphenylmethanol 
• 103164-59-6 Triphenylmethyl-1-naphthylmethan 
• 721398-51-2 1,2,2-triphenyl-acenaphthen-1-ol 

Relevant articles and documents

A one-flask synthesis of dihydronaphthalenemethanols by directed addition of organolithium reagents to BHA naphthalenecarboxylates

The 1,4-addition reaction of organolithium reagents with 2,6-bis(tert- butyl)-4-methoxyphenyl naphthalenecarboxylates gave regioselectively substituted dihydronaphthalenecarboxylates in high yields. Successive treatment of the esters with organolithiums in THF, lithium triethylborohydride, methyl iodide, and finally sodium borohydride in methanol, provided vegio- and stereoselectively the corresponding 1,1,2- and 1,2,2-trisubstituted dihydronaphthalenylmethanols in good yields. This one- flask process is constituted from a sequence of five reactions involving a reductive generation of an aldehyde metal enolate from a ketene as the key step.