1031685-80-9

Basic information

• Product Name: 5-(4-methoxyphenyl)-3,4-ethylenedioxythenyl alcohol
• Synonyms: 5-(4-methoxyphenyl)-3,4-ethylenedioxythenyl alcohol
• CAS NO: 1031685-80-9
• Molecular Weight: 278.329
• Mol File: 1031685-80-9.mol

Chemical Properties

• CAS DataBase Reference: 5-(4-methoxyphenyl)-3,4-ethylenedioxythenyl alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(4-methoxyphenyl)-3,4-ethylenedioxythenyl alcohol(1031685-80-9)
• EPA Substance Registry System: 5-(4-methoxyphenyl)-3,4-ethylenedioxythenyl alcohol(1031685-80-9)

Safety Data

• Hazardous Substances Data: 1031685-80-9(Hazardous Substances Data)

Upstream product

• 1031685-86-5 5-iodo-3,4-ethylenedioxythenyl acetate 
• 5720-07-0 4-methoxyphenylboronic acid 
• 852054-42-3 7-bromo-2,3-dihydrothieno[3,4-b][1,4]dioxine-5-carbaldehyde 

Downstream Products

• 925674-54-0 5?(4?methoxyphenyl)?2,3?dihydrothieno[3,4?b][1,4]dioxine 

Relevant articles and documents

Metal-Free Aerobic Oxidative Selective C-C Bond Cleavage in Heteroaryl-Containing Primary and Secondary Alcohols

A transition-metal-free aerobic oxidative selective C-C bond-cleavage reaction in primary and secondary heteroaryl alcohols is reported. This reaction was highly efficient and tolerated various heteroaryl alcohols, generating a carboxylic acid derivative and a neutral heteroaromatic compound. Experimental studies combined with density functional theory calculations revealed the mechanism underlying the selective C-C bond cleavage. This strategy also provides an alternative simple approach to carboxylation reaction.

Phenyl-EDOTn derivatives as super acid labile carboxylic acid protecting groups for peptide synthesis

A series of new 3,4-ethylenedioxy-2-thenyl (EDOTn) derived alcohols have been synthesized and evaluated as super acid labile carboxylic acid protecting groups. All the derivatives are labile to very low concentrations of TFA (0.01-0.5%).