10317-10-9

Basic information

• Product Name: 3-Chloro-2-methyl-1-propanol
• Synonyms: 3-Chloro-2-methyl-1-propanol
• CAS NO: 10317-10-9
• Molecular Formula: C4H9ClO
• Molecular Weight: 108.56666
• Mol File: 10317-10-9.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 122.94°C (rough estimate)
• Appearance: /
• Density: 1.0830
• Refractive Index: 1.4460
• CAS DataBase Reference: 3-Chloro-2-methyl-1-propanol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Chloro-2-methyl-1-propanol(10317-10-9)
• EPA Substance Registry System: 3-Chloro-2-methyl-1-propanol(10317-10-9)

Safety Data

• Hazardous Substances Data: 10317-10-9(Hazardous Substances Data)

Usage

Uses

3-Chloro-2-methylpropan-1-ol acts as a reagent use in the oxidation of organoboranes with sodium percarbonate

Synthesis Reference(s)

Tetrahedron Letters, 30, p. 1483, 1989 DOI: 10.1016/S0040-4039(00)99497-8

Upstream product

• 78-85-3 2-methylpropenal 
• 616-19-3 1,3-dichloro-2-methylpropane 
• 563-47-3 3-Chloro-2-methylpropene 
• 2159-71-9 1-acetoxy-3-chloro-2-methyl-propane 

Relevant articles and documents

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Primary Alcohols via Nickel Pentacarboxycyclopentadienyl Diamide Catalyzed Hydrosilylation of Terminal Epoxides

The efficient and regioselective hydrosilylation of epoxides co-catalyzed by a pentacarboxycyclopentadienyl (PCCP) diamide nickel complex and Lewis acid is reported. This method allows for the reductive opening of terminal, monosubstituted epoxides to form unbranched, primary alcohols. A range of substrates including both terminal and nonterminal epoxides are shown to work, and a mechanistic rationale is provided. This work represents the first use of a PCCP derivative as a ligand for transition-metal catalysis.

Sodium Perborate: A Mild and Convenient Reagent for Efficiently Oxidizing Organoboranes

Sodium perborate, a readily available and inexpensive reagent, efficiently oxidizes organoboranes.The reagent permits the oxidation of a wide variety of functionally substituted organoboranes.In nearly every instance, the product yields exceed those obtained using standard oxidation procedures.