1031900-67-0Relevant academic research and scientific papers
Direct synthesis of 1,3-diketones by Rh-catalyzed reductive α-acylation of enones
Sato, Kazuyuki,Yamazoe, Satoshi,Yamamoto, Rie,Ohata, Shizuka,Tarui, Atsushi,Omote, Masaaki,Kumadaki, Itsumaro,Ando, Akira
, p. 2405 - 2408 (2008)
(Chemical Equation Presented) 1,3-Diketones were synthesized from α,β-unsaturated ketones by treatment with acid chlorides and Et 2Zn in the presence of RhCl(PPh3)3. This is a very simple and extremely chemoselective reaction to give the adduct at the α-position of α,β-unsaturated ketones.
