103192-00-3Relevant academic research and scientific papers
Ozonolysis of Vinyl Ethers. Evidence for Intramolecular Oxygen Transfer from a Carbonyl Oxide Moiety to a Methoxyvinyl Group
Nakamura, Norinaga,Nojima, Masatomo,Kusabayashi, Shigekazu
, p. 4969 - 4973 (2007/10/02)
Ozonolysis of diene 1 in carbon tetrachloride gave exclusively the keto ester 2, while in methanol the keto olefin 17 was the major product.The behavior of model vinyl ethers 3a,b has revealed that a mechanism involving intramolecular oxygen atom transfer from the carbonyl oxide moiety to a methoxyvinyl group is the most probable for the keto ester formation from diene 1.
