103204-07-5

Basic information

• Product Name: 4-Iodo-3-methyl-benzoic acid ethyl ester
• Synonyms: 4-Iodo-3-methyl-benzoic acid ethyl ester;Ethyl 4-iodo-3-methylbenzoate
• CAS NO: 103204-07-5
• Molecular Formula: C₁₀H₁₁IO₂
• Molecular Weight: 290.09761
• EINECS: -0
• Mol File: 103204-07-5.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 145-147 °C(Press: 8 Torr)
• Appearance: /
• Density: 1.592±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 4-Iodo-3-methyl-benzoic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Iodo-3-methyl-benzoic acid ethyl ester(103204-07-5)
• EPA Substance Registry System: 4-Iodo-3-methyl-benzoic acid ethyl ester(103204-07-5)

Safety Data

• Hazardous Substances Data: 103204-07-5(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 52107-87-6 4-iodo-3-methylbenzoic acid 

Downstream Products

• 108478-59-7 4'-methoxy-2-methyl-biphenyl-4-carboxylic acid 

Relevant articles and documents

Palladium-Catalyzed, Norbornene-Mediated, ortho-Amination ipso-Amidation: Sequential C-N Bond Formation

A palladium-catalyzed, norbornene-mediated ortho- and ipso-C-N bond-forming Catellani reaction is reported. This reaction proceeds through a sequential intermolecular amination followed by intramolecular cyclization of a tethered amide. The products, ortho-aminated dihydroquinolinones, were generated in moderate to good yields and are present in bioactive molecules. This work highlights the challenge of competing intra- vs intermolecular palladium-catalyzed processes.