103233-16-5

Upstream product

• 76-83-5 trityl chloride 
• 115479-76-0 2,4,6-Triisopropyl-benzenesulfonic acid (2S,3S)-2-hydroxy-3-methyl-5-trityloxy-pentyl ester 
• 112031-78-4 (3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-pentane-1,4-diol 
• 99315-75-0 (-)-5-O-(diphenyl-t-butylsilyl)-2,3-O-(thiocarbonyl)-D-ribono-1,4-lactone 
• 92512-33-9 (3R,4S,5R)-5-((tert-butyldiphenylsilyloxy)methyl)-3,4-dihydroxydihydrofuran-2(3H)-one 
• 106731-86-6 (S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-3-phenylselanyl-dihydro-furan-2-one 
• 115479-75-9 3,4-dideoxy-3-C-methyl-5-O-triphenylmethyl-D-erythro-pentitol 
• 112031-78-4 3,4-dideoxy-3-C-methyl-5-O-tert-butyldiphenylsilyl-D-erythro-pentitol 
• 103233-14-3 (4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one 
• 99315-76-1 (5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone 
• 102717-29-3 (5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)dihydrofuran-2(3H)-one 
• 56-86-0 L-glutamic acid 
• 32780-06-6 (5S)-5-(hydroxymethyl)-2-oxo-tetrahydrofuran 
• 21461-84-7 (2S)-tetrahydro-5-oxofuran-2-carboxylic acid 

Downstream Products

• 112031-72-8 (R)-5-((S)-1-Methyl-3-trityloxy-propyl)-5H-furan-2-one 
• 115479-81-7 (4S,5R)-4-Methyl-5-((S)-1-methyl-3-trityloxy-propyl)-dihydro-furan-2-one 
• 103246-24-8 (S)-5-((S)-1-Methyl-3-trityloxy-propyl)-3-phenylsulfanyl-dihydro-furan-2-one 
• 103233-23-4 (3R,5R)-3,5-di-C-methyl-1-O-tert-butyldiphenylsilyl-7-O-triphenylmethyl-heptane 1,7-diol 
• 115479-85-1 (S)-3-Benzenesulfinyl-5-((S)-1-methyl-3-trityloxy-propyl)-dihydro-furan-2-one 
• 115479-79-3 (3S,4R,5S)-3,5-Dimethyl-7-trityloxy-heptane-1,4-diol 
• 103303-19-1 (3S,4S,5S)-1-(tert-Butyl-diphenyl-silanyloxy)-3,5-dimethyl-7-trityloxy-heptan-4-ol 
• 115479-80-6 Methanesulfonic acid (1S,2S)-1-[(S)-3-(tert-butyl-diphenyl-silanyloxy)-1-methyl-propyl]-2-methyl-4-trityloxy-butyl ester 
• 115479-79-3 (3R,4R,5S)-3,5-Dimethyl-7-trityloxy-heptane-1,4-diol 
• 103233-17-6 (S)-5-((S)-1-Methyl-3-trityloxy-propyl)-5H-furan-2-one 
• 103233-18-7 (4R,5S)-4-Methyl-5-((S)-1-methyl-3-trityloxy-propyl)-dihydro-furan-2-one 
• 103233-20-1 (3S,5R)-3,5-dimethyl-1-O-tert-butyldiphenylsilyl-7-O-triphenylmethyl-heptane-1,7-diol 
• 103233-19-8 (3R,4S,5S)-3,4-dimethyl-1-O-tert-butyldiphenylsilyl-7-O-triphenylmethyl-heptane-1,4,7-triol 
• 115479-80-6 Methanesulfonic acid (1S,2S)-1-[(R)-3-(tert-butyl-diphenyl-silanyloxy)-1-methyl-propyl]-2-methyl-4-trityloxy-butyl ester 

Relevant academic research and scientific papers

STEREOCHEMICAL CONTROL OF NATURE'S BIOSYNTHETIC PATHWAYS: A GENERAL STRATEGY FOR THE SYNTHESIS OF POLYPROPIONATE-DERIVED STRUCTURAL UNITS FROM A SINGLE CHIRAL PROGENITOR

A general strategy that permits the stereocontrolled construction of acyclic chains containing vicinal and/or alternating alkyl and hydroxy substituents is presented.Structural subunits of ionomycin were synthesized from a common chiral intermediate.

METHODOLOGY FOR THE POLYENE AND RELATAD ANTIBIOTICS-ENANTIOSPECIFIC SYNTHESIS OF CHIRAL STRUCTURAL UNITS OF AMPHOTERICIN B FROM A COMMON PROGENITOR:THE C14-C20 AND C32-C38 SEGMENTS

Structural units corresponding to the C14-C20 and C32-C3 segments of amphotericin B were synthesized from a single chiral progenitor.

A Tactically Novel Alternative to Acyclic Stereoselection Based on the Concept of a Replicating Chiron - 1,3- and 1,4-C-Methyl Substitution

A chiral 4-hydroxymethyl butenolide is used as a template for the stereocontrolled conjugate addition of a C-methyl group.A sequential two-carbon extension and reformation of a lactone with the new side-chain leads to a "replicated" butenolide, which is s