112031-72-8

Upstream product

• 103246-24-8 (S)-5-((S)-1-Methyl-3-trityloxy-propyl)-3-phenylsulfanyl-dihydro-furan-2-one 
• 115479-85-1 (S)-3-Benzenesulfinyl-5-((S)-1-methyl-3-trityloxy-propyl)-dihydro-furan-2-one 
• 21461-84-7 (2S)-tetrahydro-5-oxofuran-2-carboxylic acid 
• 32780-06-6 (5S)-5-(hydroxymethyl)-2-oxo-tetrahydrofuran 
• 56-86-0 L-glutamic acid 
• 102717-29-3 (5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)dihydrofuran-2(3H)-one 
• 99315-76-1 (5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone 
• 120438-32-6 Methanesulfonic acid (1S,2S)-1-(tert-butyl-diphenyl-silanyloxymethyl)-2-methyl-4-trityloxy-butyl ester 
• 103233-16-5 4,5-anhydro-2,3-dideoxy-3-C-methyl-1-O-triphenylmethyl-D-threo-pentitol 
• 103233-14-3 (4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one 
• 115479-77-1 (4S,5S)-4-Hydroxy-5-methyl-2-phenylsulfanyl-7-trityloxy-heptanoic acid 
• 103233-15-4 (2R,3S)-1-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-5-trityloxy-pentan-2-ol 
• 112031-78-4 (3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-pentane-1,4-diol 
• 76-83-5 trityl chloride 

Downstream Products

• 115479-81-7 (4S,5R)-4-Methyl-5-((S)-1-methyl-3-trityloxy-propyl)-dihydro-furan-2-one 
• 103233-23-4 (3R,5R)-3,5-di-C-methyl-1-O-tert-butyldiphenylsilyl-7-O-triphenylmethyl-heptane 1,7-diol 
• 112031-80-8 (2R,3R,4S)-4-Methyl-2-(R)-oxiranyl-6-trityloxy-hexan-3-ol 
• 112031-77-3 (2S,3S,4R,5S)-4-Methoxymethoxy-3,5-dimethyl-7-trityloxy-heptan-2-ol 
• 112031-74-0 (3S,4S,5R)-3-Hydroxy-4-methyl-5-((S)-1-methyl-3-trityloxy-propyl)-dihydro-furan-2-one 
• 112031-76-2 (R)-2-((1R,2R,3S)-2-Methoxymethoxy-1,3-dimethyl-5-trityloxy-pentyl)-oxirane 
• 112031-75-1 Methanesulfonic acid (1S,2R,3R,4S)-3-hydroxy-1-hydroxymethyl-2,4-dimethyl-6-trityloxy-hexyl ester 
• 112031-73-9 (4S,5R)-5-((S)-1-Methyl-3-trityloxy-propyl)-4-(tris-methylsulfanyl-methyl)-dihydro-furan-2-one 

Relevant academic research and scientific papers

METHODOLOGY FOR THE POLYENE AND RELATAD ANTIBIOTICS-ENANTIOSPECIFIC SYNTHESIS OF CHIRAL STRUCTURAL UNITS OF AMPHOTERICIN B FROM A COMMON PROGENITOR:THE C14-C20 AND C32-C38 SEGMENTS

Structural units corresponding to the C14-C20 and C32-C3 segments of amphotericin B were synthesized from a single chiral progenitor.

STEREOCHEMICAL CONTROL OF NATURE'S BIOSYNTHETIC PATHWAYS: A GENERAL STRATEGY FOR THE SYNTHESIS OF POLYPROPIONATE-DERIVED STRUCTURAL UNITS FROM A SINGLE CHIRAL PROGENITOR

A general strategy that permits the stereocontrolled construction of acyclic chains containing vicinal and/or alternating alkyl and hydroxy substituents is presented.Structural subunits of ionomycin were synthesized from a common chiral intermediate.

A Tactically Novel Alternative to Acyclic Stereoselection Based on the Concept of a Replicating Chiron - 1,3- and 1,4-C-Methyl Substitution

A chiral 4-hydroxymethyl butenolide is used as a template for the stereocontrolled conjugate addition of a C-methyl group.A sequential two-carbon extension and reformation of a lactone with the new side-chain leads to a "replicated" butenolide, which is s