10325-65-2Relevant academic research and scientific papers
Modular access to 1,2-allenyl ketones based on a photoredox-catalysed radical-polar crossover process
Du, Chan,Fang, Jianghua,Fang, Yewen,Lei, Wan,Li, Yan,Liu, Yongjun
supporting information, p. 8502 - 8506 (2021/10/20)
Herein, a new protocol dealing with the preparation of 1,2-allenyl ketones has been successfully developedviathe reactions of enynes with radicals enabled by dual photoredox/copper catalysis. Based on the results of a deuteration experiment and the competition reaction between cyclopropanation and allenation, the mechanism based on a photoredox-neutral-catalysed radical-polar crossover process has been proposed. Synthetic applications of allenes have also been demonstrated.
Synthesis and pharmacological evaluation of some new fluorine containing hydroxypyrazolines as potential anticancer and antioxidant agents
Dinesha,Viveka, Shivapura,Priya, Bolli Keerthi,Pai, K. Sreedhara Ranganath,Naveen, Shivalingegowda,Lokanath, Neratur K.,Nagaraja, Gundibasappa Karikannar
, p. 25 - 32 (2015/10/12)
Breast cancer is probably the most prevalent cancer in women. The development of resistance to therapeutic agents and lack of targeted therapy for breast cancer cells provide motivation to identify new compounds for the treatment. With this objective in m
GAS-SOLID REACTIONS : PART VI. INTERACTION OF SOLID CHALCONES WITH BROMINE AND IODINE VAPOURS
Hadjoudis, E.
, p. 237 - 244 (2007/10/02)
Solid chalcones (azylidene acetophenones) give, on exposure to bromine vapour at room temperature, the "trans-adduct" in quantitative or near-quantitative yield.Polymorphic forms of several compounds do not differ in their bromination products.Iodine vapours do not cause cis-trans isomerisation in the solid cis-chalcones.
