103281-80-7

Upstream product

• 10031-93-3 ethyl 4-phenylbutyrate 
• 1462-75-5 3-phenylpropylmagnesium bromide 
• 637-59-2 1-Bromo-3-phenylpropane 
• 616-38-6 carbonic acid dimethyl ester 
• 868-84-8 S,S-dimethyl dithiocarbonate 

Downstream Products

• 55282-64-9 1,7-diphenyl-4-(3-phenyl-propyl)-heptane 
• 55282-03-6 1,7-Diphenyl-4-(3-phenyl-propyl)-hept-4-en 
• 55334-73-1 1,7-dicyclohexyl-4-(3-cyclohexyl-propyl)-heptane 
• 103330-34-3 4-<3-Cyclohexyl-propyl>-1,7-diphenyl-heptan 

Relevant academic research and scientific papers

Samarium-based Grignard-type addition of organohalides to carbonyl compounds under catalysis of CuI

Grignard-type additions were readily achieved under the mediation of CuI (10 mol%) and samarium (2 equiv.) by employing various organohalides,e.g.benzyl, aryl, heterocyclic and aliphatic halides (Cl, Br or I), and diverse carbonyl compounds (e.g.carbonic esters, carboxylic esters, acid anhydrides, acyl chlorides, ketones, aldehydes, propylene epoxides and formamides) to afford alcohols, ketones and aldehydes, respectively, with high efficiency and chemoselectivity, in which the organosamarium intermediate might be involved.

S,S-dimethyl dithiocarbonate: A novel carbonyl dication synthon in the synthesis of ketones

We report herein the use of DMDTC as an effective carbonyl dication equivalent in ketone synthesis. According to our strategy, we also successfully devised a synthetic pathway for S-methyl (trimethylsilyl)thioacetate which may be a potentially useful synthetic reagent in organic synthesis.