103386-08-9Relevant academic research and scientific papers
Copper(II)-catalyzed monoarylation of vicinal diols with diaryliodonium salts
Kuriyama, Masami,Hamaguchi, Norihisa,Onomura, Osamu
, p. 1591 - 1594 (2012)
Selective and efficient: The copper(II)-catalyzed selective monoarylation of vicinal diols with diaryliodonium triflates was successfully developed. In this catalytic process high chemoselectivity was achieved, even in the presence of a 1:1 mixture of the 1,2-diol and the mono-ol, and a wide range of substrates was tolerated, giving the monoarylated products in good to excellent yields (see scheme). Copyright
Benzodioxane prostacyclin analogs
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, (2008/06/13)
Benzodioxane prostacyclin analogs represented by the formula: STR1 wherein R1 is alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, or phenoxyalkyl; R2 is hydrogen, lower alkyl, or aralkyl; R3 is hydrogen or a protecting group; A is ethylene or vinylene; and the wavy line indicates α or β configuration or their mixture; or a salt thereof having an antiulcer activity and platelet aggregation inhibitory activity.
