103409-36-5Relevant academic research and scientific papers
SELECTIVE REDUCTION OF C-C DOUBLE BONDS IN CONJUGATED ENONES BY BENZYLAMINE. A VARIANT OF THE SOMMELET REACTION
Armesto, Diego,Horspool, William M.,Martin, Juan Antonio F.,Perez-Ossorio, Rafael
, p. 5217 - 5220 (1985)
Prolonged reaction of some ketones with benzylamine at reflux converts them into α-benzyl derivatives by a route involving aldol condensation of the related ketimine with benzaldimine followed by exclusive reduction of the resultant C-C double bond by hydride transfer from benzylamine.This efficient procedure is a variant of the Sommelet reaction for the synthesis of aldehydes.
Studies on the Scope of the aza-di-?-methane Rearrangement of β,γ-Unsaturated Imines
Armesto, Diego,Langa, Fernando,Martin, Juan-Antonio Fernandez,Perez-Ossorio, Rafael,Horspool, William M.
, p. 743 - 746 (2007/10/02)
The syntheses of imines of 2,2,4,4-tetraphenylbut-3-enal, 3,3-dimethyl-5,5-diphenylpent-4-en-2-one, and 2,2-dimethyl-1,4,4-triphenylbut-3-en-1-one are described.The results of the irradiation of these and of 2,2-dimethyl-4,4-diphenylbut-3-enonitrile and 2
