Tetrahedron Letters p. 5217 - 5220 (1985)
Update date:2022-07-29
Topics:
Armesto, Diego
Horspool, William M.
Martin, Juan Antonio F.
Perez-Ossorio, Rafael
Prolonged reaction of some ketones with benzylamine at reflux converts them into α-benzyl derivatives by a route involving aldol condensation of the related ketimine with benzaldimine followed by exclusive reduction of the resultant C-C double bond by hydride transfer from benzylamine.This efficient procedure is a variant of the Sommelet reaction for the synthesis of aldehydes.
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