1034124-82-7

Upstream product

• 109-99-9 tetrahydrofuran 
• 956597-41-4 (2-Me-indenyl)2Sc(N(SiMe₃)2) 
• 1034124-79-2 (2-Me-indenyl)Sc(N(SiMe₃)2)(PhNMe₂)B(C₆F₅)4 

Relevant academic research and scientific papers

METALLOCENE COMPLEX AND POLYMERIZATION CATALYST COMPOSITION CONTAINING THE SAME

Disclosed are a metallocene complex represented by the general formula (I), (II) or (III), and a polymerization catalyst composition containing such a metallocene complex. In the formulae (I), (II) and (III), M represents a lanthanoid element, scandium or

Generation of cationic indenyl silylamide gadolinium and scandium complexes [(Ind)Ln{N(SiMe3)2}]+[B(C6F 5)4]- and their reactivity for 1,3-butadiene polymerization

Highly efficient cis-polymerization of butadiene was achieved by using new bis(indenyl) silylamide rare earth complexes with the cooperation of both a borate salt and i-Bu3Al; treatment of these complexes with organoboron compounds unexpectedly yielded new cationic mono(indenyl) amido species relevant to polymerization. The Royal Society of Chemistry.