1034402-44-2Relevant academic research and scientific papers
A mild and selective Pd-mediated methodology for the synthesis of highly fluorescent 2-arylated tryptophans and tryptophan-containing peptides: A catalytic role for Pd0 nanoparticles?
Williams, Thomas J.,Reay, Alan J.,Whitwood, Adrian C.,Fairlamb, Ian J. S.
supporting information, p. 3052 - 3054 (2014/03/21)
A Pd-mediated direct C-H bond functionalisation of tryptophan has been developed, both as a single amino acid residue and within peptides. Important mechanistic insight into this process has been gained by characterising a Pd catalytically competent nanoparticle phase which evolves during the early stages of reaction. The Royal Society of Chemistry.
Switchable reactivity of acylated α,β-dehydroamino ester in the Friedel-Crafts alkylation of indoles by changing the lewis acid
Angelini, Elena,Balsamini, Cesarino,Bartoccini, Francesca,Lucarini, Simone,Piersanti, Giovanni
, p. 5654 - 5657 (2008/12/21)
(Chemical Equation Presented) Highly regioselective electrophilic substitution of indoles with N-acetylated α,β-dehydroalanine methyl ester, promoted by different transition metal salts was achieved. The orthogonal regioselectivity provides an efficient p
