1034705-56-0Relevant academic research and scientific papers
Formation of acylruthenium promoted by coordination of AlMe3 to (η4-cyclopentadienone)Ru(CO)3
Ogoshi, Sensuke,Kato, Tetsuya,Ohashi, Masato,Kurosawa, Hideo
, p. 2232 - 2234 (2008)
The reaction of AlMe3 with (η4- tetraphenylcyclopentadienone)Ru(CO)3 leads to rapid and quantitative formation of an adduct arising from coordination of the enone oxygen to aluminium, which undergoes alkylation at the Ru(CO)3 moiety to give (η5-C4Ph4C(OAlMe2))Ru(CO) 2(COMe) concomitant with a change of hapticity of the dienone ligand. The Royal Society of Chemistry.
