Formation of acylruthenium promoted by coordination of AlMe3 to (η4-cyclopentadienone)Ru(CO)3

DOI: 10.1039/b802019c

Source and publish data:

Dalton Transactions p. 2232 - 2234 (2008)

Update date:2022-08-05

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Authors:

Ogoshi, Sensuke

Kato, Tetsuya

Ohashi, Masato

Kurosawa, Hideo

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Article abstract of DOI:10.1039/b802019c

The reaction of AlMe₃ with (η⁴- tetraphenylcyclopentadienone)Ru(CO)₃ leads to rapid and quantitative formation of an adduct arising from coordination of the enone oxygen to aluminium, which undergoes alkylation at the Ru(CO)₃ moiety to give (η⁵-C₄Ph₄C(OAlMe₂))Ru(CO) ₂(COMe) concomitant with a change of hapticity of the dienone ligand. The Royal Society of Chemistry.

Full text of DOI:10.1039/b802019c

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