10348-43-3Relevant academic research and scientific papers
Tandem Reductive Hydroformylation of Castor Oil Derived Substrates and Catalyst Recycling by Selective Product Crystallization
Furst, Marc R. L.,Korkmaz, Vedat,Gaide, Tom,Seidensticker, Thomas,Behr, Arno,Vorholt, Andreas J.
, p. 4319 - 4323 (2017)
An orthogonal tandem catalytic system consisting of rhodium and ruthenium complexes yielded linear C12 α,ω-bifunctional compounds from commercial, castor oil derived renewable substrates. With aldehyde yields up to 88 % and selectivities to the linear species of up to 95 %, this approach is direct and atom economic and provides easy access to potential polymer precursors for polycondensates. Additionally, a straightforward method for selective product crystallization was developed, which enabled recycling of the tandem catalytic system for two runs with excellent activity and simultaneously provided a high-purity product.
