1034835-89-6

Basic information

• Product Name: N-[(1R,2R)-2-[(11bS)-3,5-dihydro-4H-dinaphth[2,1-c:1',2'-e]azepin-4-yl]-1,2-diphenylethyl]-4-Methyl- BenzenesulfonaMide
• Synonyms: N-[(1R,2R)-2-[(11bS)-3,5-dihydro-4H-dinaphth[2,1-c:1',2'-e]azepin-4-yl]-1,2-diphenylethyl]-4-Methyl- BenzenesulfonaMide;N-[(1R,2R)-2-[(11bR)-3,5-Dihydro-4H-dinaphth[2,1- c:1',2'-e]azepin-4-yl]-1,2-diphenylethyl]-4- methylbenzenesulfonamide,99%e.e.
• CAS NO: 1034835-89-6
• Molecular Formula: C43H37N2O2S
• Molecular Weight: 645.83108
• Mol File: 1034835-89-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-[(1R,2R)-2-[(11bS)-3,5-dihydro-4H-dinaphth[2,1-c:1',2'-e]azepin-4-yl]-1,2-diphenylethyl]-4-Methyl- BenzenesulfonaMide(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(1R,2R)-2-[(11bS)-3,5-dihydro-4H-dinaphth[2,1-c:1',2'-e]azepin-4-yl]-1,2-diphenylethyl]-4-Methyl- BenzenesulfonaMide(1034835-89-6)
• EPA Substance Registry System: N-[(1R,2R)-2-[(11bS)-3,5-dihydro-4H-dinaphth[2,1-c:1',2'-e]azepin-4-yl]-1,2-diphenylethyl]-4-Methyl- BenzenesulfonaMide(1034835-89-6)

Safety Data

• Hazardous Substances Data: 1034835-89-6(Hazardous Substances Data)

Upstream product

• 86631-56-3 (R)-2,2'-dibromomethyl-1,1'-binaphthalene 
• 144222-34-4 (R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine 
• 37803-02-4 (S)-2,2'-bis(bromomethyl)-1,1'-binaphthyl 

Relevant articles and documents

Asymmetric Syn-selective Henry reaction catalyzed by the sulfonyldiamine-CuCl-pyridine system

(Chemical Equation Presented) A catalytic asymmetric Henry reaction has been developed with use of a sulfonyldiamine-CuCl complex as a catalyst. A series of new binaphthyl-containing sulfonyldiamine ligands (2a-h) were readily synthesized in two steps starting from commercially available chiral 1,2-diamines. The (R,R)-diamine-(R)-binaphthyl ligand (2d)-CuCl complex smoothly catalyzed the enantioselective Henry reaction with the assistance of pyridine to give the corresponding adduct with high enantiomeric excess (up to 93%). Moreover, the 2d-CuCl-pyridine system promotes the diastereoselective Henry reaction in syn-selective manner to give the adduct in up to 99% yield with 92:8 synlanti selectivity. The enantiomeric excess of the syn-adduct was 84% ee.