103516-28-5

Basic information

• Product Name: C₂₆H₂₈O₇
• CAS NO: 103516-28-5
• Molecular Weight: 452.504
• Mol File: 103516-28-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₂₆H₂₈O₇(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₂₈O₇(103516-28-5)
• EPA Substance Registry System: C₂₆H₂₈O₇(103516-28-5)

Safety Data

• Hazardous Substances Data: 103516-28-5(Hazardous Substances Data)

Upstream product

• 532-32-1 sodium benzoate 
• 103516-27-4 (2R,3R,4R,5S)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-bis<(methylsulfonyl)oxy>ethyl>-4-methyl-4-vinyltetrahydrofuran 
• 103516-13-8 2-[(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-dihydro-furo[2,3-d][1,3]dioxol-(6E)-ylidene]-ethanol 
• 103516-15-0 (2R,3R,4R,5S)-4-<(ethoxycarbonyl)methyl>-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran 
• 103537-73-1 (2R,3R,4R,5S)-4-(2-hydroxyethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran 
• 103516-24-1 (2R,3R,4R,5S)-5-<(1R)-1,2-dihydroxyethyl>-2,3-(isopropylidenedioxy)-4-methyl-4-vinyltetrahydrofuran 
• 103516-12-7 (Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose 
• 103516-20-7 3-deoxy-1,2:5,6-di-O-isopropylidene-3-C-methyl-3-C-vinyl-α-D-allofuranose 
• 57466-95-2 (E)-ethyl 2-((3aR,5S,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethylfuro[2,3-d][1,3]dioxol-6(3aH,5H,6aH)-ylidene)acetate 
• 57466-98-5 (Z)-ethyl 2-((3aR,5S,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethylfuro[2,3-d][1,3]dioxol-6(3aH,5H,6aH)-ylidene)acetate 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 57466-95-2 (E)-3-deoxy-3-C-<(ethoxycarbonyl)methylene>-1,2:5,6-di-o-isopropylidene-α-D-ribo-hexofuranose 
• 103516-19-4 (2R,3R,4R,5S)-4-(formylmethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran 
• 103516-12-7 (E)-3-deoxy-3-C-<(hydroxymethyl)methylene>-1,2:5,6-di-o-isopropylidene-α-D-ribo-hexofuranose 

Relevant articles and documents

INTRODUCTION OF gem-DIALKYL GROUP TO HEXOFURANOSE BY ORTHO ESTER CLAISEN REARRANGEMENT

The ortho ester Claisen rearrangement of D-ribo- or L-lyxo-hexofuranose derivative which possesses an allyl alcohol functionality on C-3, proceeds stereoselectively to give a 3-C-dialkylated product.The stereochemistry of a newly introduced quaternary center of the product was unambiguously established by a chemical modification.