1035346-96-3Relevant academic research and scientific papers
Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides
Van Assema, Sander G.A.,Tazelaar, Cornelis G.J.,De Bas Jong,Van Maarseveen, Jan H.,Schakel, Marius,Lutz, Martin,Spek, Anthony L.,Chris Slootweg,Lammertsma, Koop
, p. 3210 - 3215 (2009/02/03)
The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl 3 as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)5. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex.
