103559-17-7

Upstream product

• 112474-70-1 <(4-chlorophenylthio)methyl>trimethylsilane 
• 106-54-7 p-Chlorothiophenol 

Downstream Products

• 5380-97-2 2<(4-chlorophenylthio)methyl>furan 
• 112474-66-5 <1-(4-chlorophenylthio)oct-3-enyl>trimethylsilane 
• 103559-15-5 <4-chlorophenylthio(3,4-methylenedioxyphenyl)methyl>trimethylsilane 
• 112474-62-1 <4-chlorophenylthio(4-phenoxyphenyl)methyl>trimethylsilane 
• 112474-71-2 4,4'-oxybistrimethylsilane 
• 103559-13-3 <4-chlorophenylthio(3,4-dimethoxyphenyl)methyl>trimethylsilane 
• 112474-80-3 trimethylsilane 
• 112474-63-2 [(4-Chloro-phenylsulfanyl)-naphthalen-2-yl-methyl]-trimethyl-silane 
• 112474-65-4 <1-(4-chlorophenylthio)hex-3-enyl>trimethylsilane 
• 112474-67-6 <1-(4-chlorophenylthio)non-3-enyl>trimethylsilane 
• 112474-68-7 <1-(4-chlorophenylthio)undec-3-enyl>trimethylsilane 
• 103559-11-1 <4-chlorophenylthio(4-methoxyphenyl)methyl>trimethylsilane 
• 112474-78-9 <1-(4-chlorophenylsulphonyl)undec-3-enyl>trimethylsilane 
• 112489-73-3 <1-(4-chlorophenylthio)nona-1,3-dienyl>trimethylsilane 

Relevant academic research and scientific papers

Reaction of trimethylsilanes with Arenes and Alk-1-enes in the Presence of Lewis Acid: Syntheses of - and (1-Arylthioalk-3-enyl)-trimethylsilanes

Treatment of equimolar amounts of the trimethylsilanes (2) or (3) and electron-rich arenes with an equimolar amount of Lewis acid (SnCl4 or TiCl4) gave the Friedel-Crafts reaction products, trimethylsilanes (4) or (5), in high yields.Similar treatment of the chlorides (2) or (3) with alk-1-enes gave ene type products, trimethylsilanes (12) or (13), in moderate yields.Some chemical transformations of these products are also described.

Desilylative Pummerer-like Rearrangement of α-Trimethylsilyl-substituted Sulphoxides and Sulphides: Formation of α-Acyloxy and α-Halogeno Sulphides

α-Trimethylsilyl-substituted sulphoxides and sulphides undergo rearrangement with loss of the silyl group when treated respectively with trifluoroacetic anhydride and with N-halogenosuccinimide in the presence of trifluoroacetic acid, giving α-acyloxy sulphides and α-halogeno sulphides.

INTRODUCTION OF AN ARYLTHIO(TRIMETHYLSILYL)METHYL GROUP INTO ARENES BY FRIEDEL-CRAFTS REACTION: SYNTHESIS OF ARYLMETHYLTRIMETHYLSILANES

Friedel-Crafts reactions of trimethylsilanes (1a, b) with arenes gave trimethylsilanes (2a,b), which were converted into arylmethyltrimethylsilanes (3) by reduction with Raney nickel.