112489-73-3Relevant academic research and scientific papers
Reaction of trimethylsilanes with Arenes and Alk-1-enes in the Presence of Lewis Acid: Syntheses of - and (1-Arylthioalk-3-enyl)-trimethylsilanes
Ishibashi, Hiroyuki,Nakatani, Hiroshi,Umei, Yoshizumi,Yamamoto, Wako,Ikeda, Masazumi
, p. 589 - 594 (2007/10/02)
Treatment of equimolar amounts of the trimethylsilanes (2) or (3) and electron-rich arenes with an equimolar amount of Lewis acid (SnCl4 or TiCl4) gave the Friedel-Crafts reaction products, trimethylsilanes (4) or (5), in high yields.Similar treatment of the chlorides (2) or (3) with alk-1-enes gave ene type products, trimethylsilanes (12) or (13), in moderate yields.Some chemical transformations of these products are also described.
