103560-16-3Relevant academic research and scientific papers
COBALT CARBONYL CATALYZED REDUCTION OF AROMATIC NITRILES WITH A HYDROSILANE LEADING TO N,N-DISILYLAMINES
Murai, Toshiaki,Sakane, Takehiko,Kato, Shinzi
, p. 5145 - 5148 (1985)
Cobalt carbonyl catalyzed reaction of HSiMe3 with aromatic nitriles having various functional groups provided a novel route to N,N-disilylamines.
Cobalt Carbonyl Catalyzed Hydrosilylation of Nitriles: A New Preparation of N,N-Disilylamines
Murai, Toshiaki,Sakane, Takehiko,Kato, Shinzi
, p. 449 - 453 (2007/10/02)
Cobalt carbonyl catalyzed hydrosilylation of a wide variety of nitriles with HSiMe3 has been examined.The reaction generally proceeded at 60 deg C to give N,N-disilylamines in good yields.Electron-donating groups on aromatic nitriles facilitated the react
