103563-41-3

Upstream product

• 62999-73-9 [1,3]Dithian-2-yl-phosphonic acid diethyl ester 
• 103563-38-8 (4R,5R)-5-((Z)-(S)-4-Benzyloxymethoxy-1-methyl-2-trimethylsilanyl-but-2-enyl)-4-methyl-tetrahydro-furan-2-ol 
• 103563-39-9 (Z)-(3S,4S,5R)-8-Benzyloxymethoxy-1-[1,3]dithian-2-ylidene-3,5-dimethyl-6-trimethylsilanyl-oct-6-en-4-ol 
• 3587-60-8 Benzyloxymethyl chloride 
• 103590-65-4 ((E)-3-Benzyloxymethoxy-1-bromo-propenyl)-trimethyl-silane 
• 103563-35-5 (R)-(Z)-5-<(benzyloxy)methoxy>-2-methyl-3-(trimethylsilyl)-3-penten-1-ol 
• 103563-36-6 (R)-(Z)-5-<(benzyloxy)methoxy>-2-methyl-3-(trimethylsilyl)-3-pentenal 
• 103563-34-4 Methanesulfonic acid (Z)-(S)-5-benzyloxymethoxy-1-methyl-2-oxo-3-trimethylsilanyl-pent-3-enyl ester 
• 103563-67-3 (Z)-(3S,4S,5R)-8-Benzyloxymethoxy-3,5-dimethyl-4-(tetrahydro-pyran-2-yloxy)-6-trimethylsilanyl-oct-6-en-1-ol 
• 103590-67-6 [(2R,3S,4S)-1-[2-Benzyloxymethoxy-eth-(Z)-ylidene]-2,4-dimethyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-enyl]-trimethyl-silane 
• 103563-37-7 (3S,4S,5R)-(Z)-8-<(benzyloxy)methoxy>-3,5-dimethyl-3-(trimethylsilyl)-1,6-octadien-4-ol 
• 103563-33-3 (S)-(Z)-6-<(benzyloxy)methoxy>-2-hydroxy-4-(trimethylsilyl)-4-hexen-3-one 

Downstream Products

• 103563-43-5 (3R,5S,6S)-6-((E)-(S)-4-Benzyloxymethoxy-1-methyl-but-2-enyl)-3,5-dimethyl-tetrahydro-pyran-2-one 
• 103664-64-8 (3S,5S,6S)-6-((E)-(S)-4-Benzyloxymethoxy-1-methyl-but-2-enyl)-3,5-dimethyl-tetrahydro-pyran-2-one 
• 103563-42-4 (4S,5S,6S)-(E)-9-<(benzyloxy)methoxy>-4,6-dimethyl-7-nonen-5-olide 
• 103843-96-5 (2S,3S)-2-<(S)-(E)-4-<(benzyloxy)methoxy>-1-methyl-2-buten-1-yl>-1-oxa-7,11-dithiaspiro<5.5>undecane 

Relevant academic research and scientific papers

STEREOSELECTIVE SYNTHESIS OF C(1)-C(9) AND C(11)-C(17) FRAGMENTS OF PROTOMYCINOLIDE IV BASED ON ASYMMETRIC PINACOL-TYPE REARRANGEMENT

Two chiral intermediates, C(1)-C(9) and C(11)-C(17) portions of protomycinolide IV, were synthesized both from (S)-ethyl lactate via asymmetric pinacol-type rearrangement followed by diastereoselective reactions on α-methyl-β,γ-unsaturated carbonyl compounds.