103563-37-7

Upstream product

• 4784-77-4 (E/Z)-crotyl bromide 
• 103563-36-6 (R)-(Z)-5-<(benzyloxy)methoxy>-2-methyl-3-(trimethylsilyl)-3-pentenal 
• 4784-77-4 (E)-1-Bromo-2-butene 
• 31197-41-8 crotyltributylstannane 
• 3587-60-8 Benzyloxymethyl chloride 
• 96011-46-0 3-(benzyloxymethoxy)prop-1-yne 
• 103590-65-4 ((E)-3-Benzyloxymethoxy-1-bromo-propenyl)-trimethyl-silane 
• 103563-35-5 (R)-(Z)-5-<(benzyloxy)methoxy>-2-methyl-3-(trimethylsilyl)-3-penten-1-ol 
• 103563-34-4 Methanesulfonic acid (Z)-(S)-5-benzyloxymethoxy-1-methyl-2-oxo-3-trimethylsilanyl-pent-3-enyl ester 
• 103563-33-3 (S)-(Z)-6-<(benzyloxy)methoxy>-2-hydroxy-4-(trimethylsilyl)-4-hexen-3-one 

Downstream Products

• 103590-67-6 [(2R,3S,4S)-1-[2-Benzyloxymethoxy-eth-(Z)-ylidene]-2,4-dimethyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-enyl]-trimethyl-silane 
• 104416-21-9 (Z)-(3S,5R)-8-Benzyloxymethoxy-3,5-dimethyl-6-trimethylsilanyl-octa-1,6-dien-4-one 
• 103563-68-4 (E)-(3S,4S,5S)-8-Benzyloxymethoxy-3,5-dimethyl-octa-1,6-dien-4-ol 
• 103563-38-8 (4R,5R)-5-((Z)-(S)-4-Benzyloxymethoxy-1-methyl-2-trimethylsilanyl-but-2-enyl)-4-methyl-tetrahydro-furan-2-ol 
• 103664-62-6 (Z)-(3S,4R,5R)-8-Benzyloxymethoxy-3,5-dimethyl-6-trimethylsilanyl-octa-1,6-dien-4-ol 
• 103563-45-7 (8S,9S,11R)-8-((E)-(S)-4-Benzyloxymethoxy-1-methyl-but-2-enyl)-9,11-dimethyl-7-oxa-1,5-dithia-spiro[5.5]undecane 
• 103563-44-6 (E)-(4S,5S,6S)-1-Benzyloxymethoxy-8-[1,3]dithian-2-ylidene-4,6-dimethyl-non-2-en-5-ol 
• 103563-70-8 (E)-(3S,4S,5S)-8-Benzyloxymethoxy-4-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-oct-6-en-1-ol 
• 103563-69-5 [(E)-(1S,2S)-5-Benzyloxymethoxy-2-methyl-1-((S)-1-methyl-allyl)-pent-3-enyloxy]-tert-butyl-dimethyl-silane 
• 103563-72-0 (4S,5S,6S)-(E)-9-benzyloxymethoxy-5-tert-butyldimethylsilyloxy-4,6-dimethylnon-7-enyl-2-one 
• 103563-43-5 (3R,5S,6S)-6-((E)-(S)-4-Benzyloxymethoxy-1-methyl-but-2-enyl)-3,5-dimethyl-tetrahydro-pyran-2-one 
• 103664-64-8 (3S,5S,6S)-6-((E)-(S)-4-Benzyloxymethoxy-1-methyl-but-2-enyl)-3,5-dimethyl-tetrahydro-pyran-2-one 
• 103563-39-9 (Z)-(3S,4S,5R)-8-Benzyloxymethoxy-1-[1,3]dithian-2-ylidene-3,5-dimethyl-6-trimethylsilanyl-oct-6-en-4-ol 
• 103563-67-3 (Z)-(3S,4S,5R)-8-Benzyloxymethoxy-3,5-dimethyl-4-(tetrahydro-pyran-2-yloxy)-6-trimethylsilanyl-oct-6-en-1-ol 

Relevant academic research and scientific papers

HIGHLY STEREOSELECTIVE APPROACH TO CHIRAL BUILDING BLOCK POSSESSING THREE CONTIGUOUS ASYMMETRIC CENTERS. PREPARATION OF FOUR POSSIBLE DIASTEREOMERS OF β,β'-DIMETHYL-BIS-HOMOALLYLIC ALCOHOL DERIVATIVE

All four diastereomers of chiral alcohol 2 with three contiguous chiral centers were stereoselectively prepared via diastereoselective addition of nucleophiles (crotyl metal or H(1-)) to α-methyl-β,γ-unsaturated carbonyl compounds 1.