103563-72-0

Upstream product

• 141858-93-7 N-<(3S,4S,5S)-(E)-8-benzyloxymethoxy-4-hydroxy-3,5-dimethyloct-6-enoyl>pyrrolidine 
• 121896-40-0 methyl (4R,5S)-(E)-8-benzyloxy-4-tert-butyldimethylsilyloxy-5-methyl-oct-6-en-2-ynoate 
• 121896-41-1 methyl (4R,5S)-(2Z,6E)-8-benzyloxy-4-tert-butyldimethylsilyloxy-5-methylocta-2,6-dienoate 
• 111149-32-7 (E)-(4R,5S)-8-Benzyloxy-4-hydroxy-5-methyl-oct-6-en-2-ynoic acid 
• 111149-33-8 (2Z,6E)-(4S,5S)-8-Benzyloxy-4-hydroxy-5-methyl-octa-2,6-dienoic acid 
• 121896-39-7 ((E)-(1R,2S)-5-Benzyloxy-1-ethynyl-2-methyl-pent-3-enyloxy)-tert-butyl-dimethyl-silane 
• 141858-92-6 (3S,4S,5S)-(E)-8-benzyloxymethoxy-4-hydroxy-3,5-dimethyloct-6-enoic acid lactone 
• 111149-29-2 (R)-(Z)-1-benzyloxy-2-(3'-trimethylsilylpropargyloxy)-3-pentene 
• 111149-35-0 (3S,4S,5S)-(E)-8-benzyloxy-4-hydroxy-3,5-dimethyloct-6-enoic acid lactone 
• 120448-40-0 (R)-(Z)-1-benzyloxy-2-propargyloxy-3-pentene 
• 111149-34-9 (4R,5S)-(2Z,6E)-8-benzyloxy-4-hydroxy-5-methyl-2,6-octadienoic acid lactone 
• 141858-90-4 (3S,4S,5S)-(E)-4-hydroxy-8-iodo-3,5-dimethyloct-6-enoic acid lactone 
• 141858-91-5 (3S,4S,5S)-(E)-4,8-dihydroxy-3,5-dimethyloct-6-enoic acid lactone 
• 110339-29-2 (R)-(Z)-1-Benzyloxy-2-hydroxy-3-pentene 

Downstream Products

• 103563-45-7 (8S,9S,11R)-8-((E)-(S)-4-Benzyloxymethoxy-1-methyl-but-2-enyl)-9,11-dimethyl-7-oxa-1,5-dithia-spiro[5.5]undecane 
• 103563-44-6 (E)-(4S,5S,6S)-1-Benzyloxymethoxy-8-[1,3]dithian-2-ylidene-4,6-dimethyl-non-2-en-5-ol 
• 103563-43-5 (3R,5S,6S)-6-((E)-(S)-4-Benzyloxymethoxy-1-methyl-but-2-enyl)-3,5-dimethyl-tetrahydro-pyran-2-one 
• 103664-64-8 (3S,5S,6S)-6-((E)-(S)-4-Benzyloxymethoxy-1-methyl-but-2-enyl)-3,5-dimethyl-tetrahydro-pyran-2-one 
• 79495-87-7 protomycinolide IV 

Relevant academic research and scientific papers

AN ENANTIOCONTROLLED ROUTE TO PROTOMYCINOLIDE IV AND ITS PRESUMED BIOGENETIC PRECURSORS USING (S)-O-BENZYLGLYCIDOL

Starting with (S)-O-benzylglycidol (9) as only chiral building block, a formal synthesis of protomycinolide IV (1) and the first syntheses of its presumed biogenetic precursors methyl epimycinonate I (2), methyl mycinonate I (3), methyl mycinonate II (4),