120448-40-0

Upstream product

• 110339-29-2 (R)-(Z)-1-Benzyloxy-2-hydroxy-3-pentene 
• 106-96-7 propargyl bromide 

Downstream Products

• 111149-29-2 (R)-(Z)-1-benzyloxy-2-(3'-trimethylsilylpropargyloxy)-3-pentene 
• 111149-36-1 (2S,3S,4RS,5RS)-5-benzyloxymethyl-4-bromo-2-ethynyl-3-methyltetrahydrofuran 
• 111149-36-1 (2R,3S,4RS,5RS)-5-benzyloxymethyl-4-bromo-2-ethynyl-3-methyltetrahydrofuran 
• 111149-37-2 (2R,3S,4RS,5RS)-5-benzyloxymethyl-4-bromo-2-ethyl-3-methyltetrahydrofuran 
• 111149-37-2 (2S,3S,4RS,5RS)-5-benzyloxymethyl-4-bromo-2-ethyl-3-methyltetrahydrofuran 
• 141858-94-8 N-<(3S,4S,5S)-(E)-8-benzyloxymethoxy-4-tert-butyldimethylsilyloxy-3,5-dimethyloct-6-enoyl>pyrrolidine 
• 141858-93-7 N-<(3S,4S,5S)-(E)-8-benzyloxymethoxy-4-hydroxy-3,5-dimethyloct-6-enoyl>pyrrolidine 
• 121896-40-0 methyl (4R,5S)-(E)-8-benzyloxy-4-tert-butyldimethylsilyloxy-5-methyl-oct-6-en-2-ynoate 
• 103563-72-0 (4S,5S,6S)-(E)-9-benzyloxymethoxy-5-tert-butyldimethylsilyloxy-4,6-dimethylnon-7-enyl-2-one 
• 121896-41-1 methyl (4R,5S)-(2Z,6E)-8-benzyloxy-4-tert-butyldimethylsilyloxy-5-methylocta-2,6-dienoate 
• 141858-95-9 (3R,4S)-(E)-7-benzyloxymethoxy-3-tert-butyldimethylsilyloxy-4-methyl-hept-5-ene 
• 111149-32-7 (E)-(4R,5S)-8-Benzyloxy-4-hydroxy-5-methyl-oct-6-en-2-ynoic acid 
• 111149-33-8 (2Z,6E)-(4S,5S)-8-Benzyloxy-4-hydroxy-5-methyl-octa-2,6-dienoic acid 
• 121896-39-7 ((E)-(1R,2S)-5-Benzyloxy-1-ethynyl-2-methyl-pent-3-enyloxy)-tert-butyl-dimethyl-silane 

Relevant academic research and scientific papers

AN ENANTIOCONTROLLED ROUTE TO PROTOMYCINOLIDE IV AND ITS PRESUMED BIOGENETIC PRECURSORS USING (S)-O-BENZYLGLYCIDOL

Starting with (S)-O-benzylglycidol (9) as only chiral building block, a formal synthesis of protomycinolide IV (1) and the first syntheses of its presumed biogenetic precursors methyl epimycinonate I (2), methyl mycinonate I (3), methyl mycinonate II (4),