103634-03-3

Upstream product

• 110-87-2 3,4-dihydro-2H-pyran 
• 87655-21-8 (S)-3-hydroxy-2,2-dimethylcyclohexanone 
• 562-13-0 2,2-dimethyl-1,3-cyclohexanedione 

Downstream Products

• 110673-61-5 (S)-(+)-2-methoxycarbonyl-6,6-dimethyl-5-tetrahydropyranyloxycyclohexanone 
• 106540-52-7 (3S,6RS)-(+)-6-(3'-butenyl)-2,2-dimethyl-3-tetrahydropyranyloxycyclohexanone 
• 105996-61-0 (3S)-6-formyl-2,2-dimethyl-3-tetrahydropyranyloxycyclohexanone 
• 106540-53-8 (3S,6RS)-(+)-6-(3'-butenyl)-2,2,6-trimethyl-3-tetrahydropyranyloxycyclohexanone 
• 106540-54-9 (3S,6RS)-(+)-6-(3'-oxybutyl)-2,2,6-trimethyl-3-tetrahydropyranyloxycyclohexanone 
• 104435-19-0 (S)-(-)-3,3-dimethyl-4-tetrahydropyranyloxy-1-cyclohexanemethanol 
• 105996-72-3 (+)-(1S,3S)-(2,2-dimethyl-6-methylene-3-p-toluenesulfonyloxycyclohexyl)methyl p-toluenesulfonate 
• 105996-70-1 Toluene-4-sulfonic acid (1S,3S)-2,2-dimethyl-6-methylene-3-(tetrahydro-pyran-2-yloxy)-cyclohexylmethyl ester 
• 105996-76-7 (1S,3S)-2,2-dimethyl-6-methylene-3-tosyloxycyclohexanemethyl acetate 
• 105996-73-4 (1S,3S)-(+)-2,2-dimethyl-6-methylene-3-tosyloxycyclohexanemethyl formate 
• 105996-71-2 (-)-(1S,3S)-(3-hydroxy-2,2-dimethyl-6-methylenecyclohexyl)methyl p-toluenesulfonate 
• 105996-74-5 (1S,3S)-2,2-dimethyl-6-methylene-3-tetrahydropyranyloxycyclohexanemethyl acetate 
• 105996-63-2 (S)-(-)-6-n-butylthiomethylene-2,2-dimethyl-3-tetrahydropyranyloxycyclohexanone 
• 105996-64-3 (3S)-6-butylthiomethylene-2,2-dimethyl-3-tetrahydropyranyloxycyclohexan-1-ol 

Relevant academic research and scientific papers

SYNTHESIS OF BOTH THE ENANTIOMERS OF O-METHYL PISIFERIC ACID, A MITE GROWTH REGULATOR ISOLATED FROM CHAMAECYPARIS PISIFERA ENDL

Both the enantiomers of O-methyl pisiferic acid (12-methoxyabieta-8,11,13-trien-20-oic acid) were synthesized from (S)-3-hydroxy-2,2-dimethylcyclohexanone

SHYNTHESIS OF (1S,5R)-KARAHANA ETHER AND (1S,5R)-KARAHANA LACTONE. THE OPTICALLY ACTIVE FORMS OF UNIQUE MONOTERPENES WITH A 6-OXABICYCLOOCTANE RING SYSTEM

(1S,5R)-(-)-Karahana ether (8,8-dimethyl-2-methylene-6-oxabicyclooctane) and (1S,5R)-(-)-karahana lactone (8,8-dimethyl-2-methylene-6-oxabicyclooctan-7-one) were synthesized from (S)-3-hydroxy-2,2-dimethylcyclohexanone.The natural karahana lactone was shown to be almost racemic (ca. 1.3 percent e.e.).

Synthesis of (S)-2-Hydroxy-β-ionone, Employing (S)-3-Hydroxy-2,2-dimethylcyclohexanone as the Chiral Starting Material

(S)-2-Hydroxy-β-ionone of 96 percent e.e. was synthesized from (S)-3-hydroxy-2,2-dimethylcyclohexanone, which was easily obtained by the baker's yeast reduction of 2,2-dimethylcyclohexane-1,3-dione.