10366-82-2

Basic information

• Product Name: mannonic acid 1,4-lactone
• Synonyms: mannonic acid 1,4-lactone
• CAS NO: 10366-82-2
• Molecular Formula: C₆H₁₀O₆
• Molecular Weight: 0
• Mol File: 10366-82-2.mol

Chemical Properties

• Boiling Point: 467.9°Cat760mmHg
• Flash Point: 201.5°C
• Appearance: /
• Density: 1.766g/cm³
• Vapor Pressure: 1.01E-10mmHg at 25°C
• Refractive Index: 1.625
• CAS DataBase Reference: mannonic acid 1,4-lactone(CAS DataBase Reference)
• NIST Chemistry Reference: mannonic acid 1,4-lactone(10366-82-2)
• EPA Substance Registry System: mannonic acid 1,4-lactone(10366-82-2)

Safety Data

• Hazardous Substances Data: 10366-82-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H10O6/c7-1-2(8)5-3(9)4(10)6(11)12-5/h2-5,7-10H,1H2/t2-,3-,4+,5?/m1/s1

Upstream product

• 69-65-8 mannitol 
• 133-42-6 galactonic acid 
• 608-66-2 D-galactitol 
• 19242-59-2 D-galactose N,N'-diphenylformazan 

Downstream Products

• 133-42-6 gluconic acid 
• 50-99-7 galactose 
• 7306-64-1 2,3:5,6-di-O-isopropylidene-α-D-mannono-1,4-lactone 
• 1426415-10-2 (3S,4R,6S)-3,4-O-isopropylidene-6-(3,5-dinitrobenzoyloxymethyl)tetrahydro-2H-pyran-3,4-diol 
• 1426415-12-4 (3S,4R,6S)-3,4-O-isopropylidene-6-(tosyloxymethyl)tetrahydro-2H-pyran-3,4-diol 
• 40656-50-6 2,3:5,6-di-O-cyclohexylidene-D-gulonic acid γ-lactone 
• 490-83-5 L-threo-2,3-hexodiulosono-1,4-lactone 
• 121570-26-1 1-(3-chlorophenyl)-3-(1,2,3-tri-O-acetyl-L-threo-glycerol-1-yl)-4,5-pyrazoledione 4-(3-chlorophenylhydrazone) 
• 89912-70-9 5-O-acetyl-3,6-anhydro-3-C-(3-chlorophenylazo)-L-xylo-2-hexulosono-1,4-lactone 2-(3-chlorophenylhydrazone) 
• 89912-64-1 L-threo-2,3-hexodiulosono-1,4-lactone 2,3-bis(3-chlorophenylhydrazone) 
• 89912-69-6 3,6-anhydro-3-C-(3-chlorophenylazo)-L-xylo-2-hexulosono-1,4-lactone 2-(3-chlorophenylhydrazone) 
• 89912-66-3 1-(3-chlorophenyl)-3-(L-threo-glycerol-1-yl)-4,5-pyrazoledione 4-(3-chlorophenylhydrazone) 
• 89912-65-2 4-(2-acetoxyethylidene)-4-hydroxy-2,3-dioxobutano-1,4-lactone 2-(3-chlorophenylhydrazone) 
• 89912-63-0 L-threo-2,3-hexodiulosono-1,4-lactone 2-(3-chlorophenylhydrazone) 

Relevant articles and documents

A new efficient access to glycono-1,4-lactones by oxidation of unprotected itols by catalytic hydrogen transfer with RhH(PPh3)4-benzalacetone system

Treatment of unprotected pentitols and hexitols with RhH(PPh3)4-benzalacetone system leads exclusively to glycono-1,4-lactones in 60-96% yield.

2-Acetamido-2-deoxyaldonolactones from sugar formazans

A new approach towards simple aldonic acid derivatives starting from the corresponding aldoses via the 2-acetamido-2-deoxy formazans resulted in the synthesis of 2-acetamido-2-deoxy-D-galactono-1,4-lactone (8), and its 6-deoxy (11) and 6-azido-6-deoxy (14) analogues on treatment with trifluoroacetic acid.The five-membered ring structure of the lactones and that of the intermediate lactone phenylhydrazone (7) was proved by 1H and 13C NMR studies, including deuterium-induced differential isotope shift (DIS) measurements.With sodium borohydride, lactones 8 and 11 were converted into 2-acetamido-2-deoxy-D-galactitol (15) and its 6-deoxy analogue (17), respectively.